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Cleavage of the natural lignin and the dioxane lignin of kenaf by thioacetic acid

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Abstract

The dioxane lignin and the natural lignin of kenaf undergo 37.62% and 94.6% cleavage, respectively. The combined monomeric degradation products have been studied by the GLC method. The presence of substances relating to three types of structural units has been established: p-coumaryl, gualacyl, and syringyl. It has been shown by chromatography on Sephadex LH-20 (with ethanol-water (9:1) as solvent and eluent) that the phenolic products of degradation extracted by ethyl acetate at pH 2 consist of five fractions: oligomers, tetramers, trimers, dimers, and monomers.

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Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 234–235, March–April, 1986.

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Dalimova, G.N., Abduazimov, K.A. Cleavage of the natural lignin and the dioxane lignin of kenaf by thioacetic acid. Chem Nat Compd 22, 218–219 (1986). https://doi.org/10.1007/BF00574745

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  • DOI: https://doi.org/10.1007/BF00574745

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