Abstract
Infrared spectra were recorded of CH3OH, C2H,5OH, HCOOH, CH3COOH, CH3COOC2H5, (C2H5)2O, CH3CHO, CH3CHCHCHO, and CH3CHCHCOOH sorbed on MgO powder at 25°. In addition to being physically adsorbed, all adsorbates reacted extensively with the surfaces. There was a general trend for the chemisorbed species to form surface carboxylates.
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Anderson, P. J., Horlock, R. F., and Oliver, J. F.: 1965,Trans. Far. Soc. 61, 2754.
Arai, H., Saito, Y., and Yoneda, Y.: 1967,Bull. Chem. Soc. Japan 40, 731.
Arai, H., Saito, Y., and Yoneda, Y.: 1968,J. Catalysis 10, 128.
Bellamy, L. J.: 1964,The Infra-red Spectra of Complex Molecules, 2nd ed., Wiley, New York, 1964; a, p. 145; b, p. 162.
Blyholder, G. and Neff, L. D.: 1966,J. Phys. Chem. 70, 1738.
Goodsel, A. J., Low, M. J. D., and Takezawa, N.: 1972,Environ. Sci. Technol. 6, 268.
Greenler, R. G.: 1962,J. Chem. Phys. 37, 2094.
Kagel, R. O. and Greenler, R. G.: 1968,J. Chem. Phys. 49, 1638.
Little, L. H.: 1966,Infrared Spectra of Adsorbed Species, Academic Press, New York, p. 77.
Low, M. J. D., Goodsel, A. J., and Takezawa, N.: 1971,Environ. Sci. Technol. 5, 1191.
Nakamoto, K.: 1963,Infrared Spectra of Inorganic and Coordination Compounds, Wiley, New York, p. 216.
Scholten, J. J. F. Mars, P., Menon, P. G., and Van Hardeveld, R.: 1964,Proc. 3rd Int. Congr. Catalysis, Vol. 2, p. 881.
Young, R. P. and Sheppard, N.: 1967a, J. Catalysis7, 223.
Young, R. P. and Sheppard, N.: 1967b,Trans. Far. Soc. 63, 2291.
Young, R. P. and Sheppard, N.: 1971,J. Catalysis 20, 340.
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Part II: Goodselet al. (1972).
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Low, M.J.D., Jacobs, H. & Takezawa, N. Reactions of gaseous pollutants with solids. Water Air Soil Pollut 2, 61–73 (1973). https://doi.org/10.1007/BF00572390
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DOI: https://doi.org/10.1007/BF00572390