Advertisement

Chemistry of Natural Compounds

, Volume 11, Issue 3, pp 385–388 | Cite as

Synthesis of glycosides of gypsogenin and of gypsogenic acid by the orthoester method

  • V. G. Bukharov
  • S. P. Shcherbak
Article
  • 30 Downloads

Summary

1. Gypsogenin 3-β-D-glucopyranoside has been obtained for the first time.

2. The natural 3-(β-D-xylopyranoside) of gypsogenic acid (saponaroside) has been synthesized.

Keywords

Nitromethane Xylosyl Xyloside Lithium Iodide Acid Dimethyl Ester 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    N. K. Kochetkov, A. Ya. Khorlin, and Yu. S. Ovodov, Izv. Akad. Nauk SSSR, No. 8, 1437 (1964).Google Scholar
  2. 2.
    K. Amanmuradov and N. K. Abubakirov, Khim. Prirodn. Soedin., 372 (1965).Google Scholar
  3. 3.
    V. Ya. Chirva and P. K. Kintya, Khim. Prirodn. Soedin., 214 (1970).Google Scholar
  4. 4.
    V. G. Bukharov and S. P. Shcherbak, Khim. Prirodn. Soedin., 420 (1971).Google Scholar
  5. 5.
    V. G. Bukharov and L. N. Karneeva, Khim. Prirodn. Soedin., 412 (1971).Google Scholar
  6. 6.
    A. Ya. Khorlin, Yu. S. Ovodov, and N. K. Kochetkov, Zh. Obshch. Khim.,32, 782 (1962).Google Scholar
  7. 7.
    A. Ya. Khorlin, A. F. Bochkov, and N. K. Kochetkov, Khim. Prirodn. Soedin., 6 (1966).Google Scholar
  8. 8.
    N. I. Uvarova, G. I. Oshitok, V. V. Isakov, A. K. Dzizenko, and G. V. Elyakov, Dokl. Akad. Nauk SSSR,202, No. 2, 368 (1972).Google Scholar
  9. 9.
    L. G. Kretsu, Author's Abstract of Candidate's Dissertation, Kishinev (1974).Google Scholar
  10. 10.
    N. K. Kochetkov, A. Ya. Khorlin, and V. I. Snyatkova, Izv. Akad. Nauk SSSR, Ser. Khim., 2028 (1964).Google Scholar
  11. 11.
    V. G. Bukharov and S. P. Shcherbak, Izv. Akad. Nauk SSSR, Ser. Khim., No. 1, 137 (1969).Google Scholar
  12. 12.
    V. I. Belous and A. A. Ryabinin, Khim. Prirodn. Soedin., 95 (1967).Google Scholar
  13. 13.
    N. K. Kochetkov, A. Ya. Khorlin, and A. F. Bochkov, Zh. Obshch. Khim.,37, 388 (1967).Google Scholar
  14. 14.
    P. G. Scheurer and F. Smith, J. Amer. Chem. Soc.,76, 3224 (1967).CrossRefGoogle Scholar
  15. 15.
    N. K. Kochetkov, A. Ja. Khorlin, and A. F. Bochkov, Tetrahedron,23, 693 (1967).CrossRefGoogle Scholar
  16. 16.
    H. G. Fletscher and C. S. Hudson, J. Amer. Chem. Soc.,69, 921 (1947).CrossRefGoogle Scholar

Copyright information

© Plenum Publishing Corporation 1976

Authors and Affiliations

  • V. G. Bukharov
  • S. P. Shcherbak

There are no affiliations available

Personalised recommendations