Chemistry of Natural Compounds

, Volume 15, Issue 1, pp 4–6 | Cite as

13C NMR spectra of acetylated methyl glycosides of monosaccharides

  • A. I. Kalinovskii
  • E. V. Evtushenko
Article

Summary

A comparative discussion of the signals in the13C NMR spectra of acetylated methyl α- and β-D-xylopyranosides, α- and β-D-glucopyranosides, α- and β-D-galactopyranosides, α- and β-L-arabinopyranosides, α- and β-L-fucopyranosides, and α- and β-L-rhamnopyranosides and of the corresponding free glycosides has shown a similarity of the effects of substitution at C5 with a longer-range nature of these effects in the case of the acetylated glycosides.

Keywords

Methyl Organic Chemistry Glycoside Monosaccharide Comparative Discussion 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    A. S. Shashkov and O. S. Chizhov, Bioorg. Khim.,2, 437 (1976).Google Scholar
  2. 2.
    P. A. J. Gorin and M. Mazurek, Can. J. Chem.,53, 1212 (1975).Google Scholar
  3. 3.
    D. E. Dorman and J. D. Robirts, J. Am. Chem. Soc.,93, 4463 (1971).Google Scholar
  4. 4.
    K. Tori, S. Seo, Y. Yoshimuro, H. Arita, and Y. Tomita, Tetrahedron Lett., 179 (1977).Google Scholar
  5. 5.
    D. Y. Jaghaike, F. R. Tarvel, and M. B. Vignon, Carbohydr. Res.,51, 157 (1976).Google Scholar
  6. 6.
    K. Izumi, J. Biochem.,76, 535 (1974).Google Scholar
  7. 7.
    P. L. Durette and D. Horton, Carbohydr. Res.,18, 403 (1971).Google Scholar
  8. 8.
    J. Stanek, M. Cerny, J. Kocourek, and J. Pacak, The Monosaccharides, Academic Press, New York (1963), p. 500.Google Scholar
  9. 9.
    E. V. Evtushenko and Yu. S. Ovodov, Khim. Prir. Soedin., 87 (1976).Google Scholar

Copyright information

© Plenum Publishing Corporation 1979

Authors and Affiliations

  • A. I. Kalinovskii
  • E. V. Evtushenko

There are no affiliations available

Personalised recommendations