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Chemistry of Natural Compounds

, Volume 17, Issue 3, pp 244–248 | Cite as

Structure and stereochemistry of lapidin

  • L. A. Golovina
  • A. I. Saidkhodzhaev
Article
  • 22 Downloads

Abstract

The roots ofFerula lapidosa Eug.Korov. have yielded lapidin, C20H30O4, mp 80–81°C (hexane), [α]D20 +166° (c 1.5; chloroform) — an ester of a new carotane alcohol lapidol and angelic acid. A structure and absolute configuration has been suggested for it on the basis of chemical transformations and spectral characteristics.

Keywords

Absolute Configuration Thionyl Chloride Olefinic Proton Isopropyl Group Sodium Tetrahydroborate 

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Literature cited

  1. 1.
    G. V. Sagitdinova, A. I. Saidkhodzhaev, G. K. Nikonov, and U. Rakhmankulov, Khim. Prir. Soedin., 115 (1975).Google Scholar
  2. 2.
    G. V. Sagitdinova, A. I. Saidkhodzhaev, and V. M. Malikov, Khim. Prir. Soedin., 161 (1979).Google Scholar
  3. 3.
    M. C. Sriraman, B. A. Nagasampagi, R. C. Pandey, and Sukh Dev, Tetrahedron,29, 985 (1973).CrossRefGoogle Scholar
  4. 4.
    A. I. Saidkhodzhaev, and G. K. Nikonov, Khim. Prir. Soedin., 559 (1972); 28 (1973); 166 (1974); 105 (1976).Google Scholar

Copyright information

© Plenum Publishing Corporation 1982

Authors and Affiliations

  • L. A. Golovina
  • A. I. Saidkhodzhaev

There are no affiliations available

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