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Chemistry of Natural Compounds

, Volume 7, Issue 5, pp 629–632 | Cite as

The structure of sibirosamine — A new amino sugar from the antibiotic sibiromycin

  • A. S. Mezentsev
  • V. V. Kulyaeva
  • L. M. Rubasheva
  • M. G. Brazhnikova
  • O. S. Anisimova
  • T. V. Vlasova
  • Yu. N. Sheinker
Article
  • 32 Downloads

Summary

1. It has been shown that the antitumoral antibiotic sibiromycin is a glycoside of a new amino sugar which has been called sibirosamine.

2. It has been established that sibirosamine is a 3-C-methyl-4-methylamino-4,6-dideoxyhexopyranose, i.e., a new amino sugar differing from all the amino sugars known hitherto by the branching of the carbon skeleton.

Keywords

Periodate Acetic Anhydride CD3OD Amino Sugar White Amorphous Powder 

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Literature cited

  1. 1.
    M. G. Brazhnikova, I. N. Kovsharova, N. V. Konstantinova, A. S. Mezentsev, V. V. Proshlyakova, and I. V. Tolstykh, Antibiotiki,4, 297 (1970).Google Scholar
  2. 2.
    W. Steglich and G. Höfle, Angew. Chem.,23, 1001 (1969).CrossRefGoogle Scholar
  3. 3.
    H. Budzikiewicz, C. Djerassi, and D. Williams, Interpretation of Mass Spectra of Organic Compounds, Holden-Day, San Francisco (1964).Google Scholar

Copyright information

© Consultants Bureau 1974

Authors and Affiliations

  • A. S. Mezentsev
  • V. V. Kulyaeva
  • L. M. Rubasheva
  • M. G. Brazhnikova
  • O. S. Anisimova
  • T. V. Vlasova
  • Yu. N. Sheinker

There are no affiliations available

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