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Glycosides ofVaccaria segetalis

III. Enzymatic and alkaline cleavage of vacsegoside

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Summary

The enzymatic hydrolysis of vaccegoside, a triterpene glycoside fromVaccaria segetalis, has given D-glucose, D-xylose, D-glucuronic acid, an unknown disaccharide, and a 28-O-acyltetraoside of gypsogenin, esterified with sugars at the carboxyl group, containing D-glucose, D-rhamnose, L-arabinose, and D-xylose. It has been shown that the disaccharide has the structure 4-(D-xylopyranosido)-D-glucopyranose. The alkaline hydrolysis of vacsegoside yielded a gypsogenin tetraoside-vaccarotertraoside. The structure of vaccarotetraoside has been established as gypsogenin-(3)-β-D-glucopyranuronosido-(4 or 2)-D-glucopyranosido-(3)-D-glucopyranosido-(4) d-xylopyranose.

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References

  1. N. K. Abubakirov and K. Amanmuradov, ZhOKh, 34, 1661, 1964.

    CAS  Google Scholar 

  2. K. Amanmuradov and N. K. Abubakirov, Izv. AN TurkmSSR, ser. FTKh i GN, 6, 106, 1964.

    Google Scholar 

  3. Ya. V. Rashkes, ZhAKh, 20, 238, 1965.

    CAS  Google Scholar 

  4. G. N. Zaitseva and T. P. Afanas'eva, Biokhim., 22, 1035, 1957.

    CAS  Google Scholar 

  5. K. Macek, in: Paper Chromatography [Russian translation], Moscow, 285, 1962.

  6. A. Ya. Khorlin, L. V. Bakinovskii, V. S. Vas'kovskii, A. G. Ven'yaminova, and Yu. S. Ovodov, Izv. AN SSSR, 11, 2008, 1963.

    Google Scholar 

  7. H. Bredereck, G. Hagelloch, and E. Hambsch, Ber., 87, 35 (1954).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Institute of the Chemistry of Plant Substances AS UzSSR, USSR

    K. Amanmuradov & N. K. Abubakirov

  2. Institute of Chemistry AS TurkmSSR, USSR

    K. Amanmuradov & N. K. Abubakirov

Authors
  1. K. Amanmuradov
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  2. N. K. Abubakirov
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Additional information

Khimiya Prirodnykh Soedinenii, Vol. 1, No. 6, pp. 372–379, 1965.

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Amanmuradov, K., Abubakirov, N.K. Glycosides ofVaccaria segetalis . Chem Nat Compd 1, 292–296 (1965). https://doi.org/10.1007/BF00568295

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  • DOI: https://doi.org/10.1007/BF00568295

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