Summary
The reaction of pyridine and hydrochloric acid with grosshemin in the presence of acetic anhydride forms a substance with the composition C20H24O4NCl · H2O, mp 160–165°C, [α] D20 + 71.23 (c 1.33; water), for which structure (II) is proposed.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
S. V. Hiromath, G. H. Kulkarni, G. R. Kelkar, and S. C. Bhattacharyya, Ind. J. Chem.,6, No. 6, 339 (1973).
L. Drajanowska-Noninska, P. Todorowa-Avramowa, E. Najdenowa, and L. Lobutowa, Pharmazie, No. 8 543 (1973).
E. D. Bergman, D. Ginsburg, and R. Pappo, Organic Reactions,10, 179 (1959).
W. Herz, K. Veda, and S. Inayama, Tetrahedron,19, No. 3, 483 (1963).
S. C. Srivastava, S. K. Paknikar, and S. C. Bhattacharyya, Ind. J. Chem.,8, No. 2, 201 (1970).
Additional information
All-Union Scientific-Research Institute of Medicinal Plants, Moscow. Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 306–309, May–June, 1976.
Rights and permissions
About this article
Cite this article
Rybalko, K.S., Evstratova, R.I. & Sheichenko, V.I. Production of a pyridine derivative of grosshemin. Chem Nat Compd 12, 272–274 (1976). https://doi.org/10.1007/BF00567795
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/BF00567795