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Chemistry of Natural Compounds

, Volume 4, Issue 1, pp 10–14 | Cite as

Synthesis of triterpene glycosides

II. Synthesis of acyl glycosides of 18β- and 18α-glycyrrhetic acids
  • A. M. Yuodvirshis
  • A. T. Troshchenko
Article

Summary

The acyl α-D-glucopyranoside, the acyl α-D-xylopyranoside, the acyl D- and L-α-arabinopyranosides, and the acyl β-D-lactoside of 18β-glycyrrhetic acid, and also the acyl β-D-lactoside of 18α-glycyrrhetic acid have been synthesized. The acid and alkaline hydrolysis of the compounds obtained has been studied.

Keywords

Gypsum Ursolic Acid Sodium Methoxide Glycyrrhetie Acid TRITERPENE Glycoside 

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References

  1. 1.
    A. M. Yuodvirshis and A. T. Troshchenko, KhPS [Chemistry of Natural Compounds], 405, 1966.Google Scholar
  2. 2.
    H. Bredereck, A. Wagner, H. Kuhn, and H. Ott, Ber., 93, 1203, 1960.Google Scholar
  3. 3.
    G. Zemplen and E. Pacsu, Ber., 62, 1613, 1929.Google Scholar
  4. 4.
    G. Wagner and P. Nuhn, Die Pharmazie, 21, no. 4, 205, 1966.Google Scholar
  5. 5.
    B. Helferich and L. Forsthoff, Ber., 94, 158, 1961.Google Scholar
  6. 6.
    W. Klyne, “Optical rotation,” in A. F. Braude and F. C. Nachod. Determination of Organic Structures by Physical Methods, Acad. Press, N. Y., 73, 1955.CrossRefGoogle Scholar
  7. 7.
    I. P. Kovalev and V. I. Litvinenko, KhPS [Chemistry of Natural Compounds], 233, 1965.Google Scholar
  8. 8.
    S. Barker, E. Bourne, R. Stephens, and D. Whiffen, J. Chem. Soc., 3468, 1954.Google Scholar
  9. 9.
    G. Drefahl and S. Huneck, Ber., 94, 2015, 1961.Google Scholar
  10. 10.
    J. Beaton and F. Spring, J. Chem. Soc., 3126, 1955.Google Scholar
  11. 11.
    R. Ness, H. Fletcher, and C. S. Hudson, J. Am. Chem. Soc., 72, 2200, 1950.CrossRefGoogle Scholar
  12. 12.
    M. Barczai-Martos and F. Korösy, Nature, 165, 369, 1950.CrossRefGoogle Scholar
  13. 13.
    T. Harris, E. Hirst, and C. Wood, J. Chem. Soc., 2108, 1932.Google Scholar
  14. 14.
    E. Fischer, Ber., 26, 2406, 1893.Google Scholar
  15. 15.
    H. Fletcher and C. S. Hudson, J. Am. Chem. Soc., 69, 921, 1947.CrossRefGoogle Scholar
  16. 16.
    H. Fletcher and C. S. Hudson, J. Am. Chem. Soc., 69, 1146, 1947.Google Scholar
  17. 17.
    H. Fletcher and C. S. Hudson, J. Am. Chem. Soc., 72, 4173, 1950.CrossRefGoogle Scholar
  18. 18.
    N. Albon and D. Gross, Analyst, 77, 410, 1952.CrossRefGoogle Scholar

Copyright information

© The Faraday Press, Inc 1969

Authors and Affiliations

  • A. M. Yuodvirshis
    • 1
  • A. T. Troshchenko
    • 1
  1. 1.Novosibirsk Institute of Organic Chemis Siberian Division, AS USSRUSSR

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