57Fe Mössbauer spectra and spin-crossover behavior of [Fe(mbpN)(lut)]BPh4
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New spin-crossover complexes [Fe(III)L(lut)]BPh4 (L = mbpN or bpN) with N4O2 moiety are reported. The structure of the mbpN (N3O2 quinquedentate ligand) complex is determined at 293 K, and the temperature dependences of the57Fe Mössbauer spectra and magnetic susceptibilities for both complexes have been examined.
KeywordsQuadrupole Splitting Electric Field Gradient BPh4 M6ssbauer Spectrum Electric Field Gradient Tensor
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- Y. Maeda, Y. Takashima, N. Matsumoto and A. Ohyoshi, J. Chem. Soc. Dalton Trans. (1986) 1115.Google Scholar