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Chemistry of Natural Compounds

, Volume 12, Issue 2, pp 201–202 | Cite as

Structure of herboxine

  • G. V. Chkhikvadze
  • M. M. Khalmirzaev
  • V. Yu. Vachnadze
  • V. M. Malikov
  • S. Yu. Yunusov
Article

Summary

A new hydroxyindole alkaloid has been isolated from the roots and epigeal part ofVinca herbaceae — herboxine, C23H28N2O6, [α]D +40° (c 1.13; methanol).

On the basis of UV, IR, NMR, and mass spectroscopy and a transition from majdine to herboxine, structure (I) has been proposed for it which differs from that of majdine by the configuration at C3.

Keywords

Mass Spectrum Alkaloid Benzene Ring HMDS Epigeal Part 

Literature cited

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    V. Yu. Vachnadze, V. M. Malikov, K. S. Mudzhiri, and S. Yu. Yunusov, Khim. Prirodn. Soedin., 341 (1972).Google Scholar
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    J. Ognyanov, B. Pyuskyulev, J. Kompis, T. Striczay, G. Spiteller, M. Shamma, and R. J. Shine, Z. Naturforsch.,23, 282 (1968).CrossRefGoogle Scholar
  3. 3.
    M. M. Khalmirzaev, V. M. Malikov, and S. Yu. Yunusov, Khim. Prirodn. Soedin., 806 (1973).Google Scholar

Copyright information

© Plenum Publishing Corporation 1977

Authors and Affiliations

  • G. V. Chkhikvadze
  • M. M. Khalmirzaev
  • V. Yu. Vachnadze
  • V. M. Malikov
  • S. Yu. Yunusov

There are no affiliations available

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