Summary
On the basis of a complete x-ray structural investigation, the structural formula of (+)-excelsine has been refined and its absolute configuration has been determined.
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Literature cited
V. A. Tel'nov, M. S. Yunusov, and S. Yu. Yunusov, Khim. Prirodn. Soedin., 129 (1973).
S.-M. Nasirov, V. G. Andrianov, Yu. T. Struchkov, V. A. Tel'nov, M. S. Yunusov, and S. Yu. Yunusov, Khim. Prirodn. Soedin., 812 (1974).
N. G. Bokii, Yu. T. Struchkov, D. N. Kravtsov, and E. M. Rokhlina, Zh. Strukt. Khim.,14, 291 (1973).
H. P. Hanson, F. Herman, J. D. Lea, and S. Skillman, Acta Crystallogr.,17, 1040 (1964).
V. I. Andrianov, B. L. Tarnopol'skii, and Z. Sh. Safina, Roentgen-70. Automated System of Programs for X-Ray Structural Calculations [in Russian], OIKhF, Akad. Nauk SSSR, Moscow (1972).
A. N. Chekhlov, Yu. T. Struchkov, and A. I. Kitaigorodskii, Zh. Strukt. Khim.,15, 754 (1974).
A. N. Chekhlov, Yu. T. Struchkov, and A. I. Kitaigorodskii, Zh. Strukt. Khim.,15, 917 (1974).
D. T. Cromer and D. Liberman, J. Chem. Phys.,53, 1891 (1970).
J. A. McMillan et al., Tetrahedron Lett.,5, 419 (1974).
G. I. Birnbaum, Acta Crystallogr.,B26, 755 (1970).
K. S. Pitzer and W. E. Donath, J. Amer. Chem. Soc.,81, 3213 (1959).
S.-M. Nasirov, V. G. Andrianov, Yu. T. Struchkov, and S. Yu. Yunusov, Khim. Prirodn. Soedin., 197 (1976) [in this issue].
R. S. Cahn, C. Ingold, and V. Prelog, Angew. Chem. Int. Ed.,5, 385 (1966).
M. Przybylska and L. Marion, Canad. J. Chem.,34, 189 (1956);37, 1843 (1959); M. Przybylska, Acta Crystallogr.,14, 429 (1961).
M. Przybylska and L. Marion, Canad. J. Chem.,37, 1116 (1959); M. Przybylska, Acta Crystallogr.,14, 429 (1961).
L. Marion, Pure Appl. Chem.,6, 621 (1963); R. Anet et al., Canad. J. Chem.,36, 766 (1958).
O. E. Edwards et al., Canad. J. Chem.,36, 1097 (1958).
K. Wienser et al., Tetrahedron Lett., No. 3, 11 (1959).
K. Wienser et al., Tetrahedron Lett., No. 2, 15 (1959).
W. Klyne and V. Prelog, Experientia,16, 523 (1960).
N. L. Alinger, J. Amer. Chem. Soc.,81, 5727 (1959).
Tables of Interatomic Distances and Configurations in Molecules and Ions, Chemical Society, London (1958).
T. Sato and H. Koyama, J. Chem. Soc.,B, 1070 (1971).
J. Donohue, in: Structural Chemistry and Molecular Biology, San Francisco (1968).
W. C. Hamilton and J. A. Ibers, Hydrogen Bonding in Solids, W. A. Benjamin, New York (1968).
Additional information
Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow. Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 206–217, March–April, 1976.
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Nasirov, S.M., Andrianov, V.G., Struchkov, Y.T. et al. X-ray structural investigation of alkaloids. III. Molecular structure and absolute configuration of (+)-excelsine. Chem Nat Compd 12, 184–193 (1976). https://doi.org/10.1007/BF00566341
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DOI: https://doi.org/10.1007/BF00566341