Chemistry of Natural Compounds

, Volume 4, Issue 3, pp 136–138 | Cite as

Structure of anabasamine

  • S. Z. Mukhamedzhanov
  • Kh. A. Aslanov
  • A. S. Sadykov
  • V. B. Leont'ev
  • V. K. Kiryukhin
Article

Conclusions

1. A spectroscopic study of anabasamine, isolated from the seeds of the plantAnabasis aphylla L. has been carried out.

On the basis of UV, IR, NMR, and mass spectroscopic data, the structure 5-(N-methyl-2′-piperidyl)-2,3′-bipyridyl has been proposed as the most probable.

2. The structural formula of anabasamine has been confirmed experimentally through the production of 2,3′-bipyridyl-5-carboxylic acid by the oxidation of the base.

Keywords

Piperidine Copper Powder Manganese Dioxide Bipyridyl Potassium Permanganate 

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References

  1. 1.
    Kh. A. Aslanov, S. Z. Mukhamedzhanov, and A. S. Sadykov, Nauchnye Trudy TashGU. Khimiya rastitel'nykh veshchestv,2, no. 286, 71, 1966.Google Scholar
  2. 2.
    S. Z. Mukhamedzhanov, A. S. Sadykov, and Kh. A. Aslanov, DAN UzSSR, no. 4, 34, 1967.Google Scholar
  3. 3.
    V. B. Leont'ev, O. S. Otroshchenko, Yu. S. Mangutova, and A. S. Sadykov, ZhOKh,35, 297, 1965.Google Scholar
  4. 4.
    F. A. Kramer and R. West, J. Phys. Chem.,69, 673, 1965.CrossRefGoogle Scholar
  5. 5.
    G. Budzikiewicz, C. Djerassi, and D. Williams, Interpretation of Mass Spectra of Organic Compounds [Russian translation], Moscow, p. 131, 1966.Google Scholar
  6. 6.
    A. S. Sadykov, The Chemistry of the Alkaloids ofAnabasis aphylla L. [in Russian], Tashkent, p. 35, 1956.Google Scholar
  7. 7.
    O. S. Otroshchenko and A. S. Sadykov, ZhOKh,24, 1685, 1954.Google Scholar

Copyright information

© The Faraday Press, Inc. 1971

Authors and Affiliations

  • S. Z. Mukhamedzhanov
    • 1
  • Kh. A. Aslanov
    • 1
  • A. S. Sadykov
    • 1
  • V. B. Leont'ev
    • 1
  • V. K. Kiryukhin
    • 1
  1. 1.Lenin Tashkent State UniversityUSSR

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