Chemistry of Natural Compounds

, Volume 14, Issue 4, pp 381–385 | Cite as

Transformation products of sclareol IV. Stereochemistry and mass-spectrometric fragmentation of some bicyclohomofarnesane oxides

  • P. F. Vlad
  • Kh. Sh. Khariton
  • M. N. Koltsa


The stereochemistries of three oxides of the bicyclohomofarnesane series have been established by spectral and chemical methods.


Chiral Center Chromium Trioxide Dehydration Product Oxide Oxygen Sclareol 


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Literature cited

  1. 1.
    P. F. Vlad and G. V. Lazur'evskii, Bicyclic Diterpenoids [in Russian], RIO AN MSSR, Kishiev (1968).Google Scholar
  2. 2.
    V. N. Belov, N. A. Daev, N. I. Skvortsova, and E. K. Smol'yaninova, Usp. Khim.,26, 96 (1967).Google Scholar
  3. 3.
    V. N. Belov and N. I. Skvortsova, Usp. Khim.,32, 263 (1963).Google Scholar
  4. 4.
    V. E. Sibirtseva, S. D. Kustova, and S. I. Virezub, Ref. Zh. Khim.,8R, 483 (1973).Google Scholar
  5. 5.
    M. Stoll and M. Hinder, Helv. Chim. Acta,33, 1380 (1950).Google Scholar
  6. 6.
    V. E. Sibirtseva, S. D. Kustova, S. I. Birezub, and S. A. Voitkevich, Ref. Zh. Khim.,3N, 423 (1962).Google Scholar
  7. 7.
    M. Stoll and M. Hinder, Helv. Chim. Acta,37, 1859 (1954).CrossRefGoogle Scholar
  8. 8.
    M. Stoll, M. Hinder, and E. Palluy, Helv. Chim. Acta,34, 1664 (1951).CrossRefGoogle Scholar
  9. 9.
    M. Hinder and M. Stoll, Helv. Chim. Acta,36, 1995 (1953).CrossRefGoogle Scholar
  10. 10.
    J. Jacobus, J. Org. Chem.,38, 403 (1973).CrossRefGoogle Scholar
  11. 11.
    D. Bethell and V. Gold, Carbonium Ions, Academic Press, New York (1967).Google Scholar

Copyright information

© Plenum Publishing Corporation 1979

Authors and Affiliations

  • P. F. Vlad
  • Kh. Sh. Khariton
  • M. N. Koltsa

There are no affiliations available

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