Chemistry of Natural Compounds

, Volume 17, Issue 5, pp 470–473 | Cite as

Ion-exchange properties of ammoniated lignin

  • Yu. N. Forostyan


The oxidative ammonolysis of hydrolysis lignin from sunflower husks has given ion-exchange materials with amphoteric properties. The greatest total exchange capacity of the sample with respect to 0.1 N caustic soda solution amounted to 11.5 meq/g, and with respect to 0.1 N hydrochloric acid solution to 0.6 meq/g. The processes of ion exchange with heavy-metal cations are accompanied by complex formation. The bond of the metal cations with the lignin in the complexes is effected through nitrogen and the oxygen of a nonalcoholic group.


Hydrochloric Acid Solution Caustic Soda Dimethyl Sulfate Hydrolysis Lignin Caustic Soda Solution 


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    V. R. Yauizems, V. N. Sergeeva, and L. N. Mozheiko, Izv. Akad. Nauk LatvSSR, Ser. Khim., No. 5, 629 (1967).Google Scholar
  2. 2.
    V. D. Davydova, G. A. Tedoradze, G. Ya. Tysyachnaya, and I. A. Razmanova, in: 6th All-Union Conference on the Chemistry and Use of Lignin. Abstracts of Lectures [in Russian], Riga (1976), p. 122.Google Scholar
  3. 3.
    D. G. Garkusha, P. M. Kuznetsova, and R. S. Fogileva, Zh. Anal. Khim.29, No. 11, 2295 (1974).Google Scholar
  4. 4.
    B. V. Koval'chuk and Yu. N. Porostyan, Khim. Prirodn. Soedin., 380 (1972).Google Scholar
  5. 5.
    Yu. N. Forostyan and E. I. Forostyan, Gidroliz. Lesokhim. Promst., No. 3, 28 (1976).Google Scholar
  6. 6.
    Yu. N. Forostyan, A. A. Sekatskii, and L. I. Dudnik, Gidroliz. Lesokhim., No. 2, 14 (1979).Google Scholar
  7. 7.
    K. M. Saldadze, A. B. Pashkov, and V. S. Titov, High-Molecular-Weight Ion-Exchange Compounds [in Russian] (1960), p. 17.Google Scholar
  8. 8.
    K. M. Saldadze, Z. T. Demanterik, and Z. V. Klimova, in: Investigations in the Field of Ion-Exchange Chromatography [in Russian], Moscow (1957), p. 48.Google Scholar
  9. 9.
    G. F. Zakis and B. Ya. Barzdyn', Khim. Drev.,5, 98 (1970).Google Scholar
  10. 10.
    J. Marton and E. Adler, Acta Chem. Scand.,15, 370 (1961).CrossRefGoogle Scholar
  11. 11.
    J. Marton, E. Adler, and K. Persson, Acta Chem. Scand.,15, 384 (1961).CrossRefGoogle Scholar
  12. 12.
    Yu. S. Pilipichuk, R. Z. Pen, and A.V. Finkel'shtein, Khim. Drev.,1, 45 (1968).Google Scholar
  13. 13.
    A. K. Babko and A. G. Pilipenko, Colorimetric Analysis [in Russian], Moscow (1951), p. 285.Google Scholar
  14. 14.
    V. B. Karklin' and P. P. Érin'sh, Khim. Drev.7, 83 (1971).Google Scholar
  15. 15.
    H. L. Hergert, J. Org. Chem.,25, 405 (1960).CrossRefGoogle Scholar

Copyright information

© Plenum Publishing Corporation 1982

Authors and Affiliations

  • Yu. N. Forostyan

There are no affiliations available

Personalised recommendations