Features of the splitting out of substituents from ring a of lycoctonine alkaloids on electron impact
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Summary
A mass spectrometric method for determining the configuration of the substituent at C-1 in the lycoctonine alkaloids has been proposed. The mass spectra of the carbinolamine ethers of three diterpene alkaloids have been studied. The possibility of using these spectra for determining the nature of the substituent at C-4 has been shown.
Keywords
Acrolein Mass Spectrometric Method Methoxymethylene Diterpene Alkaloid LycoctoninePreview
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Literature cited
- 1.M. S. Yunusov, Ya. V. Rashkes, V. A. Tel'nov, and S. Yu. Yunusov, Khim. Prirodn. Soedin.,5, 515 (1969).Google Scholar
- 2.M. S. Yunusov, Ya. V. Rashkes, and S. Yu. Yunusov, Khim. Prirodn. Soedin.,7 (1971).Google Scholar
- 3.M. A. Khaimova, M. D. Palamareva, N. M. Mollov, and V. P. Krestev, Tetrahedron,27, 4, 819 (1971).CrossRefGoogle Scholar
- 4.K. Wiesner, E. W. K. Jay, and Lizzie Jay (Poon), Tetrahedron Lett.,13, 867 (1971).Google Scholar
- 5.O. Achmatovicz, Jr., Y. Tsuda, and L. Marion, Can. J. Chem.,43, No. 8, 2336 (1965).CrossRefGoogle Scholar
- 6.M. S. Yunusov, Ya. V. Rashkes, S. Yu. Yunusov, and A. S. Samatov, Khim. Prirodn. Soedin.,6, 101 (1970).Google Scholar
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