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Chemistry of Natural Compounds

, Volume 9, Issue 5, pp 595–599 | Cite as

Use of the paramagnetic-shift agent Eu(DPM)3 to study the PMR spectra and stereochemistry of arnifolin

  • V. I. Sheichenko
  • V. F. Zakharov
  • V. P. Zvolinskii
  • R. I. Evstratova
  • K. S. Rybalko
Article
  • 27 Downloads

Summary

1. The configuration of the OH group has been determined and the configurations of a number of other protons in the arnifolin molecule have been confirmed by means of the paramagnetically induced PMR spectra.

2. The paramagnetic shifts of a number of protons can be explained satisfactorily if it is assumed that the predominant association of the Eu(DPM)3 is with the hydroxy group.

Keywords

Hydroxy Group Sesquiterpene Lactone INDOR Method Oxetane Paramagnetic Shift 

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Copyright information

© Plenum Publishing Corporation 1975

Authors and Affiliations

  • V. I. Sheichenko
  • V. F. Zakharov
  • V. P. Zvolinskii
  • R. I. Evstratova
  • K. S. Rybalko

There are no affiliations available

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