Chemistry of Natural Compounds

, Volume 9, Issue 5, pp 583–585 | Cite as

Structure of mogoltone, a new elemanone from Ferula mogoltavica and F. samarcandica

  • T. Kh. Khasanov
  • A. M. Saidkhodzhaev
  • G. K. Nikonov
Article
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Summary

From the roots ofFerula mogoltavica Lipsky andF. samarcandica Eug. Kor. has been isolated a new elemanone C15H24O2 with mp 95–96°C, [α] D 23 +166°, which has been called mogoltone. On the basis of the UV, IR, and NMR spectra, its ORD curve, and its reduction products, the most probable structure and configuration of mogoltone are considered to be 7-hydroxy-7-isopropyleleman-6-one with the C7-OH in the axial position and the C5-H in the equatorial position.

Keywords

Hydroxy Group Methine Proton Cyclic Ketone Sodium Tetrahydroborate Splitting Constant 

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Literature cited

  1. 1.
    J. Emsley, J. Feeney, and L. Sutcliffe, High Resolution NMR Spectroscopy, Pergmanon Press, Oxford (1965–6).Google Scholar
  2. 2.
    C. Djerassi, Optical Rotatory Dispersion, McGraw-Hill, New York (1960).Google Scholar

Copyright information

© Plenum Publishing Corporation 1975

Authors and Affiliations

  • T. Kh. Khasanov
  • A. M. Saidkhodzhaev
  • G. K. Nikonov

There are no affiliations available

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