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Chemistry of Natural Compounds

, Volume 8, Issue 3, pp 353–359 | Cite as

Infrared spectra of cyclic hexapeptides constructed of L(D)-alanine and glycine residues

  • G. A. Kogan
  • V. M. Tul'chinskii
  • V. V. Shilin
  • V. T. Ivanov
Article

Summary

By IR spectroscopy in the middle and far regions of the spectrum it has been found that on being heated with KBr a number of cyclic hexapeptides with L(D)-alanine and glycine residues undergo a transition from a mixture of various conformers into a monotypical conformational state corresponding to the “pleated sheet” structure with two trans-annular hydrogen bonds of the 4 → 1 type.

Keywords

Conformational State Glycine Residue CsBr Conformational Parameter Pleated Sheet 

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Copyright information

© Consultants Bureau 1974

Authors and Affiliations

  • G. A. Kogan
  • V. M. Tul'chinskii
  • V. V. Shilin
  • V. T. Ivanov

There are no affiliations available

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