Abstract
Emission characteristics of Ho3+-doped heavy-metal oxide and chalcogenide glasses were investigated and compared with those of conventional oxide glasses. In addition to the fluorescence at approximately 1.2 μm (5/6 → 5/8) and 2.0 μm (5/7 → 5/8), another mid-infrared emission was observed at 2.9 μm from the transition 5/6 → 5/7. The calculated radiative transition probability and multiphonon decay rate of the latter transition using Judd-Ofelt analysis indicated that the occurrence of the 2.9 μm fluorescence was directly related to the low vibrational phonon energy of the host glasses.
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W. H.Dumbaugh andJ. C.Lapp,J. Am. Ceram. Soc. 75 (1992) 2315.
W. H.Dumbaugh,Phys. Chem. Glasses 27 (1986) 119.
W.-H.Hung, C. S.Ray andD. E.Day,J. Am Ceram. Soc. 77 (1994) 1017.
F.Miyaji andS.Sakka,J. Non-Cryst. Solids 134 (1991) 77.
F.Miyaji, K.Tadanaga, T.Yoko andS.Sakka,J. Non-Cryst. Solids 139 (1992) 268.
T.Miyashita andT.Manabe,IEEE J. Quantum Electron. QE 18 (1982) 1432.
J. A.Savage,Mater. Sci. Rep. 2 (1987) 99.
R.Reisfeld, J.Hormadaly andA.Murenevich,Chem. Phys. Lett. 38 (1976) 188.
R.Reisfeld, andJ.Hormadaly,J. Chem. Phys. 64 (1976) 3207.
J.Hormadaly andR.Reisfeld,Chem.Phys. Lett. 45 (1977) 436.
R.Reisfeld, J.Hormadaly andA.Murenevich,J. Non-Cryst. Solids 29 (1978) 323.
B. R.Judd,Phys. Rev. 127 (1962) 750.
G. S.Ofelt,J. Chem. Phys. 37 (1962) 511.
M. J.Weber, B. H.Matsinger, V. L.Donlan andG. T.Surratt,J. Chem. Phys. 57 (1972) 562.
K.Tanimura, M. D.Shinn, W. A.Sibley, M. G.Drexhage andR. N.Brown,Phys. Rev. B 30 (1984) 2429.
R.Reisfeld,Ann. Chim Fr. 7 (1982) 147.
Y.Subramanyam, L. R.Moorthy andS. V. J.Lakshman,J. Non-Crosyt. Solids 139 (1992) 67.
R.Reisfeld, E.Greenberg, R. N.Brown andM. G.Drexhage,Chem Phys. Lett. 95 (1983) 91.
C. B.Layne, W. H.Lowdermilk andM. J.Weber,Phys. Rev. B 16 (1977) 10.
R.Reisfeld,Chem. Phys. Lett. 118 (1985) 25.
G.Lucovsky, F. L.Galeener, R. C.Keezer, R. H.Geils andH. A.Six,Phys. Rev. B 10 (1974) 5134.
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Shin, Y.B., Jang, J.N. & Heo, J. Mid-infrared light emission characteristics of Ho3+-doped chalcogenide and heavy-metal oxide glasses. Opt Quant Electron 27, 379–386 (1995). https://doi.org/10.1007/BF00563573
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DOI: https://doi.org/10.1007/BF00563573