Skip to main content
SpringerLink
Log in

Preparation, molecular-crystal structure, and chemical peculiarities of the potassium salt of 3,3,6,6-tetramethyl-1,8-dioxo-1,2, 3,4,5,6,7,8,9,10-decahydroacridine-9-carboxylic acid

  • Published:
Chemistry of Heterocyclic Compounds Aims and scope

Abstract

It was established by x-ray diffraction analysis that the crystalline title compound exists as a dimer formed by two paired potassium ions bonded to the oxygen atoms of the carboxy group and the coordinated oxygen atoms of the carbonyl groups. The solvate of the dimer with the composition 2C18H22NO4K·3H2O·CH3COCH3 is the crystallochemically independent structural unit. A shift of the electron density toward the carbonyl groups and the formation of a strong hydrogen bond between NH and the oxygen atom of the carboxylate group are observed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. G. Ya. Dubur and G. Ya. Vanag, Izv. Akad. Nauk Latv. SSR, Ser. Khim., No. 1, 119 (1962).

    Google Scholar 

  2. L. S. Geita, Yu. Yu. Popel, and G. Ya. Vanag, Khim. Geterotsikl. Soedin., No. 1, 26 (1967).

    Google Scholar 

  3. G. Ya. Dubur and Ya. R. Uldrikis, Khim. Geterotsikl. Soedin., No. 6, 1015 (1969).

    Google Scholar 

  4. R. J. Highet and J. F. Biellmann, J. Org. Chem.37, 3731 (1972).

    Google Scholar 

  5. J. Krajewski, Z. Urbanczyk-Lipkowska, and P. Gluzinski, Acta Cryst.,B33, 2967 (1967).

    Google Scholar 

  6. Y. F. Freimanis and É. I. Stankevich, Zh. Prikl. Spectrosk.,11, 124 (1969).

    Google Scholar 

  7. D. C. Philips, W. H. Ahmed, and W. H. Barnes, Acta Cryst.,13, 365 (1960).

    Google Scholar 

  8. A. Achari and S. Neidle, Acta Cryst.,B33, 3269 (1977).

    Google Scholar 

  9. A. Gordon and R. Ford, Chemist's Companion: A Handbook of Practical Data, Techniques, and References, Wiley (1973).

  10. A. F. Mishnev, A. E. Shvets, Ya. Ya. Bleidelis, G. Ya. Dubur, A. É. Sausin', and V. K. Lusis, Khim. Geterotsikl. Soedin., No. 9, 1229 (1977).

    Google Scholar 

  11. G. D. Smith, W. L. Duax, and S. Fortier, J. Am. Chem. Soc.,100, 6725 (1978).

    Google Scholar 

  12. G. Germain, P. Main, and M. M. Woolfson, Acta Cryst.,A27, 368 (1971).

    Google Scholar 

  13. É. I. Stankevich and G. Ya. Vanag, Zh. Org. Khim.,1, 809 (1965).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, 226006, Riga

    M. F. Bundule, É. A. Bisenieks, A. A. Kemme, Ya. Ya. Bleidelis, G. Ya. Dubur & Ya. R. Uldrikis

Authors
  1. M. F. Bundule
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. É. A. Bisenieks
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. A. Kemme
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Ya. Ya. Bleidelis
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. G. Ya. Dubur
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Ya. R. Uldrikis
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 666–672, May, 1980.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bundule, M.F., Bisenieks, É.A., Kemme, A.A. et al. Preparation, molecular-crystal structure, and chemical peculiarities of the potassium salt of 3,3,6,6-tetramethyl-1,8-dioxo-1,2, 3,4,5,6,7,8,9,10-decahydroacridine-9-carboxylic acid. Chem Heterocycl Compd 16, 519–525 (1980). https://doi.org/10.1007/BF00561352

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00561352

Keywords

Search

Navigation