Abstract
X-ray analysis at 20–1200°C and differential thermal analysis have been used to refine the transformation temperatures and unit-cell parameters for crystalline modifications of dicalcium silicate. Phase equilibria have been identified in the Ca2SiO4-CaZrO3 system at 1100–2500°C. The phase diagram for this system has been derived. The characteristic features are the eutectic form for the liquidus and the formation of narrow solid-solution regions based on various crystalline modifications of Ca2SiO4.
Similar content being viewed by others
References
N. Claussen and M. Ruhle, “Design of transformation-toughened ceramics,” Advances in Ceramics, A. H. Heuer and L. W. Hobbs (eds.), American Ceramic Society, Columbus (1981), Vol. 3, pp. 137–163.
P. F. Becher, M. V. Swain, and M. K. Ferber, “Relation of transformation temperature to the fracture toughness of transformation-toughened ceramics,” J. Mat. Sci.,22, No. 1, 76–84 (1987).
A. H. Heuer, M. Ruhle, and D. B. Marshall, “On the thermoelastic martensitic transformation in tetragonal ZrO2,” J. Amer. Ceram. Soc.,73, No. 4, 1084–1093 (1990).
A. I. Boikova, Solid Solutions of Cement Materials [in Russian], Nauka, Leningrad (1974).
Ch.-J. Chan, W. M. Kriven, and J. F. Goung, “Physical stabilization of the β-γ transformation in dicalcium silicate,” J. Amer. Ceram. Soc.,75, No. 6, 1621–1627 (1992).
D. L. Callahan, G. Thomas, J. S. Moya, and P. Pena, “Reaction sintering of Ca2SiO4-CaZrO3 composites,” J. Eur. Ceram. Soc.,9, No. 5, 397–404 (1992).
L. M. Lopato, A. V. Shevchenko, and A. E. Kushchevskii, “Research on highly refractory oxide systems,” Poroshl. Metall., No. 1, 88–92 (1972).
A. V. Zyrin, V. P. Red'ko, L. M. Lopato, et al., “Ordered phases in the systems ZrO2-Sc2O3 and HfO2-Sc2O3,” Izv. Akad. Nauk SSSR, Neorg. Materialy,23, No. 8, 1325–1329 (1987).
A. V. Shevchenko, L. M. Lopato, G. I. Gerasimyuk, and Z. A. Zaitseva, “The HfO2-CaO system,” Izv. AN SSSR, Neorg. Mater.,17, No. 5, 838–841 (1981).
Additional information
Institute of Materials Science, Ukrainian Academy of Sciences, Kiev. Translated from Poroshkovaya Metallurgiya, Nos. 9–10, pp. 55–59, September–October, 1995.
Rights and permissions
About this article
Cite this article
Lopato, L.M., Red'ko, V.P., Lakiza, S.N. et al. Interactions in the Ca2SiO4-CaZrO3 system. Powder Metall Met Ceram 34, 539–543 (1996). https://doi.org/10.1007/BF00559964
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00559964