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High-temperature synthesis of tungsten carbide in a methane-hydrogen gas medium

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Abstract

Tungsten carbide synthesis in a methane-hydrogen medium have been studied and the conditions for obtaining WC power with no free-carbon impurity determined. Hard alloys based on a “gas” carbide have been shown to exhibit high ductility. The results of the study have been used to develop a commercial process to produce high-ductile hard alloys for high-pressure equipment, stamping dies, and drilling tools.

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References

  1. V. I. Tret'yakov, V. K. Senchikhin, N. K. Vaskevich, and T. B. Gorbacheva, “Influence of cobalt on methane carbidizing of tungsten,” Poroshk. Metall., No. 11, 32–37 (1990).

  2. S. Takatsu, “A new continuous process for production of WC-Co mixed powder by rotary kilns,” Powder Met. Int.,10, No. 1, 13–15 (1978).

    Google Scholar 

  3. F. P. Gortsema and P. S. Kotvall, “The preparation of ‘precursor-derived’ WC-Co powder and the properties of cemented carbide cuttings tools made therefrom,” Planseeberichte fur Pulvermet,24, No. 4, 254–270 (1976).

    Google Scholar 

  4. S. Takatsu, “Effect of cobalt on the carburization rate of tungsten,” J. Jpn. Inst. Met.,43, No. 4, 281–286 (1979).

    Google Scholar 

  5. V. P. Bondarenko and É. G. Pavlotskaya, “Study of the interaction of sintered VK6 hard alloys with a protective gaseous medium,” in: Proceedings of Fourth International Conference on Powder Metallurgy, Vysokie Tatry, Czechoslovak Socialist Republic (1974), pp. 67–80.

  6. A. S. Petukhov, I. V. Uvarova, V. P. Bondarenko, et al., “Laws of low-temperature synthesis of tungsten carbide and a mixture of WC-Co in a methane—hydrogen gaseous medium,” Poroshk. Metall., No. 10, 31–35 (1992).

  7. V. A. Ivensen, Sintering Phenomenology [Russian translation], Metallurgiya, Moscow (1985).

    Google Scholar 

  8. K. Becker, “Die Konstitution der Wolframkarbide,” Z. fur Electrochemie,34, No. 9, 640–642 (1928).

    Google Scholar 

  9. G. A. Meerson and A. N. Zelikman, Metallurgy of Rare Metals [in Russian], Metallurgiya, Moscow (1955).

    Google Scholar 

  10. M. G. Loshak, “Strength and longevity of hard alloys,” Naukovn. Dumka, Kiev (1984).

    Google Scholar 

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Institute of Ultrahard Materials, Ukrainian Academy of Sciences Kiev. Translated from Poroshkovaya Metallurgiya, Nos. 9–10, pp. 21–26, September–October, 1995.

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Bondarenko, V.P., Pavlotskaya, É.G. High-temperature synthesis of tungsten carbide in a methane-hydrogen gas medium. Powder Metall Met Ceram 34, 508–512 (1996). https://doi.org/10.1007/BF00559958

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  • DOI: https://doi.org/10.1007/BF00559958

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