Skip to main content
SpringerLink
Log in

Magnetooptic activity and symmetry of petroleum vanadyl porphyrins

  • Optics And Spectroscopy
  • Published:
Russian Physics Journal Aims and scope

Abstract

We report magnetooptic rotation and magnetic circular dichroism spectra in the vicinity of the absorption bands at 17410 cm−1 and 16760 cm−1 in chloroform solutions of petroleum vanadyl porphyrin. Using the moment method, we estimate the original splitting and the z-component of the magnetic moment of the 11E1u level for both synthetic and petroleum vanadyl porphyrins. We conclude that petroleum vanadyl porphyrins exhibit D2h symmetry.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. K. N. Solov'ev, L. L. Gladkov, A. S. Starukhin, and S. F. Shkirman, Spectroscopy of Porphyrins: Vibrational States [in Russian], Nauka i Tekhnika, Minsk (1985), pp. 22, 38.

    Google Scholar 

  2. K. A. Askaron, B. D. Berezin, R. P. Evstigneeva, et al., Porphyrins: Structure, Properties, and Synthesis [in Russian], Nauka, Moscow (1985), pp. 12, 50.

    Google Scholar 

  3. N. S. Enikolopyan (ed.), Porphyrins: Spectroscopy, Electrochemistry, and Applications [in Russian], Nauka, Moscow (1987).

    Google Scholar 

  4. Yu. A. Sharonov, Molecular Biology [in Russian], Vol. 8, Itogi Nauki i Tekhniki (1976), Part 1, pp. 70–161.

  5. A. A. Latyshev, V. N. Medvedev, and A. V. Nerezov, Izv. Vyssh. Uchebn. Zaved., Fiz., No. 1, 80–85 (1992).

  6. V. N. Medvedev, Opt. Spektrosk.,42, No. 1, 129–135 (1977).

    Google Scholar 

  7. C. H. Henry, S. E. Snetterly, and C. P. Slichter, Phys. Rev.,137, No. 2A, 583–602 (1965).

    Google Scholar 

  8. A. D. Buckingam and P. J. Stephens, Ann. Rev. Phys. Chem.,17, 399–412 (1966).

    Google Scholar 

Download references

Authors
  1. A. A. Latyshev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. N. Medvedev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. O. Nekuchaev
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Industrial Institute, Ukhtinsk. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 11, pp. 10–14, November, 1992.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Latyshev, A.A., Medvedev, V.N. & Nekuchaev, V.O. Magnetooptic activity and symmetry of petroleum vanadyl porphyrins. Russ Phys J 35, 1004–1008 (1992). https://doi.org/10.1007/BF00559093

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00559093

Keywords

Search

Navigation