Fibre Chemistry

, Volume 23, Issue 1, pp 70–73 | Cite as

The swelling of Nigma fibres

  • V. N. Smirnova
  • M. A. Kop'ev
  • M. M. Iovleva
Physico-Mechanical Properties And Application Of Man-Made Fibres
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Conclusions

-- It has been found that the primary swelling of fibres prepared from solutions of cellulose curpimonium complex has an extremal dependency on the composition of the aqueous—organic precipitation bath.

-- The character of the dependence of the swelling of the finished CuC and HC fibres on composition of the mixed precipitant indicates a structural memory of the fibre during the transition CuAC → CuC → HC.

-- The extremal character of the temperature dependence of swelling of HC fibres in a solvent + precipitant mixture is probably brought about by several oppositely directed processes, including complex formation, change in solubility, ionization, etc.

Keywords

Polymer Precipitation Cellulose Complex Formation Structural Memory 

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Literature cited

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    S. G. Efimova, N. T. Butyagin, and N. Yu. Dolgopolova, Khim. Volokna, No. 6, 32–34 (1987).Google Scholar
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    A. A. Grinberg, Introduction to the Chemistry of Complex Compounds [in Russian], Khimiya, Leningrad (1971).Google Scholar
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    S. I. Banduryan, Candidate's Dissertation, VNIIV, Mytishchi (1972).Google Scholar
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    M. M. Iovleva, I. R. Kasevich, V. N. Smirnova, L. V. Avrorova, G. I. Kudryavtsev, and S. P. Papkov, Khim. Volokna, No. 5, 34–35 (1987).Google Scholar

Copyright information

© Plenum Publishing Corporation 1991

Authors and Affiliations

  • V. N. Smirnova
  • M. A. Kop'ev
  • M. M. Iovleva

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