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Chemistry of Heterocyclic Compounds

, Volume 16, Issue 7, pp 730–735 | Cite as

Porphyrins. 13. Reaction of meso-dimethylaminomethyletioporphyrin I with nucleophiles in the presence of zinc acetate

  • G. V. Ponomarev
Article
  • 41 Downloads

Abstract

When meso-dimethylaminomethyletioporphyrin I (I) is heated in CCl4 or tetrahydrofuran (THF) in the presence of zinc acetate, it reacts with alcohols to give the corresponding meso-alkoxy-methylporphyrins. Under similar conditions CH acids (acetone, acetylacetone, nitromethane, and others) form the corresponding meso-substituted derivatives with the formation of a C-C bond. Ethers are formed when the copper and nickel complexes of I are heated in ethylene glycol.

Keywords

Copper Alcohol Acetate Ether Zinc 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1981

Authors and Affiliations

  • G. V. Ponomarev
    • 1
  1. 1.Institute of BiophysicsMinistry of Public Health of the USSRMoscow

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