Abstract
When meso-dimethylaminomethyletioporphyrin I (I) is heated in CCl4 or tetrahydrofuran (THF) in the presence of zinc acetate, it reacts with alcohols to give the corresponding meso-alkoxy-methylporphyrins. Under similar conditions CH acids (acetone, acetylacetone, nitromethane, and others) form the corresponding meso-substituted derivatives with the formation of a C-C bond. Ethers are formed when the copper and nickel complexes of I are heated in ethylene glycol.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
L. B. Lazukova, T. A. Babushkina, G. V. Ponomarev, and G. B. Maravin, Khim. Geterotsikl. Soedin., No. 6, 769 (1980).
G. V. Ponomarev, Khim. Geterotsikl. Soedin., No. 1, 90 (1977).
V. M. Mamaev, I. P. Gloriozov, and G. V. Ponomarov, Summaries of Papers Presented at the All-Union Conference on the Physical and Coordination Chemistry of Porphyrins [in Russian], Ivanovo (1979), p. 157.
G. V. Ponomarev, V. G. Yashunskii, T. A. Babushkina, and B. V. Rozynov, USSR Inventor's Certificate No. 509586; Byul. Izobr., 53, 13 (1976).
A. Gordon and R. Ford, Chemist's Companion: A Handbook of Practical Techniques, and References, Wiley, (1973).
K. M. Smith and G. M. F. Bisset, J. Org. Chem.,44, 2077 (1979).
G. V. Ponomarev and B. V. Rozynov, Khim. Geterotsikl. Soedin, No. 9, 1172 (1973).
Author information
Authors and Affiliations
Additional information
See [1] for Communication 12.
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 943–948, July, 1980.
Rights and permissions
About this article
Cite this article
Ponomarev, G.V. Porphyrins. 13. Reaction of meso-dimethylaminomethyletioporphyrin I with nucleophiles in the presence of zinc acetate. Chem Heterocycl Compd 16, 730–735 (1980). https://doi.org/10.1007/BF00557748
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00557748