Conclusions
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Additions of water to spinning solutions of an acrylonitrile copolymer in dimethylformamide increase the rate and temperature for their gelation.
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In spinning from such solutions, the process of fibre solidification takes place by two mechanisms — a diffusion mechanism and a “cooling” mechanism.
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Addition of water to the spinning solution shifts the solidification process in the direction of the “cooling” mechanism, which leads to obtaining a more uniform and better oriented fibre.
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Literature cited
É. A. Pakshver, in: Carbochain Fibres, K. E. Perepelkin (ed.) [in Russian], Khimiya, Moscow (1973).
R. A. Polatovskaya, A. B. Pakshver, and É. A. Pakshver, in: Synthetic Fibres [in Russian], Khimiya, Moscow (1969).
V. N. Sarmadzhieva, D. Nedelcheva, and M. Kastan'o, Third Int. Symp. on Man-Made Fibres, Kalinin (1981). Preprints, Vol. 1, p. 89.
É. A. Pakshver, A. D. Kolbanovskii, L. S. Gerasimova, and V. D. Fikhman, Fourth Int. Symp. on Man-Made Fibres, Kalinin (1986). Preprints, Vol. 4, p. 247.
D. P. Nedelcheva, T. A. Belousova, et al., Vysokomol. Soed., Ser. A,28, No. 1, 195 (1986).
É. A. Pakshver, Khim. Volokna, No. 5, 10 (1976).
Additional information
Translated from Khimicheskie Volokna, No. 1, pp. 25–27, January–February, 1992.
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Pakshver, É.A., Barsukov, I.A., Kireeva, N.K. et al. Increasing the property uniformity of polyacrylonitrile fibres by adding water to spinning solutions. Fibre Chem 24, 33–36 (1992). https://doi.org/10.1007/BF00557175
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DOI: https://doi.org/10.1007/BF00557175