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Ceramic fibres from polymer precursor containing Si-O-Ti bonds

Part II Synthesis of various types of ceramic fibres

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Abstract

Polycarbosilanes containing titanium alkoxide as pendant groups (atom ratio Ti/Si = 0.07 and 0.15) were synthesized. These polymers were melt-spun and then heat-treated in a vacuum, in oxygen or ammonia gas flow, resulting in Si-Ti-C-O, Si-Ti-0 and Si-Ti-O-N fibres, respectively. The pyrolysis process of the polymer is discussed in connection with the mechanical properties and the structure of the fibre. At high heat-treatment temperatures, β-SiC and TiC (in Si-Ti-C-O fibre), anatase (in Si-Ti-O fibre) and TiN (in Si-Ti-O-N fibre) crystallized, which may be closely related to the decomposition of the Si-O-Ti bond in the fibre.

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References

  1. Y.-C. Song, Y. Hasegawa, S.-J. Yang andM. Sato,J. Mater. Sci. 23 (1988) 1911.

    Article  CAS  Google Scholar 

  2. H. Ichikawa, F. Machino, S. Mitsuna, T. Ishikawa, K. Okamura andY. Hasegawa,ibid. 21 (1986) 4352.

    Article  CAS  Google Scholar 

  3. Y. Hasegawa andK. Okamura,ibid. 18 (1983) 3633.

    Article  CAS  Google Scholar 

  4. Y. Hasegawa,ibid. 24 (1989) 1177.

    Article  CAS  Google Scholar 

  5. K. Kamiya, S. Sakka andN. Tashiro,Yogyo-Kyokai-Shi 84 (1976) 614.

    Article  CAS  Google Scholar 

  6. K. Kamiya, S. Sakka andS. Ito,ibid. 85 (1977) 599.

    Article  CAS  Google Scholar 

  7. Y. Abe, T. Gunji, M. Hikita, Y. Nagao andT. Misono,ibid. 94 (1986) 1243.

    Article  CAS  Google Scholar 

  8. S. Sakka,Hyomen 19 (1981) 430.

    CAS  Google Scholar 

  9. W. C. LaCourse, “Better Ceramics Through Chemistry”, edited by C. J. Brinker, D. E. Clark and D. R. Ulrich (North-Holland, Amsterdam, 1984) p. 53.

    Google Scholar 

  10. K. Kamiya, K. Tanimoto andT. Yoko.J. Mater. Sci. Lett. 5 (1986) 402.

    Article  CAS  Google Scholar 

  11. T. Maki, T. Kokubo andS. Sakka,Bull. Inst. Chem. Res. Kyoto Univ. 64 (1986) 292.

    CAS  Google Scholar 

  12. Y. Abe, N. Sugimoto, Y. Nagao andT. Misono,J. Non-Cryst. Solids 104 (1988) 292.

    Article  Google Scholar 

  13. S. Sakka andK. Kamiya,ibid. 42 (1980) 403.

    Article  CAS  Google Scholar 

  14. K. Okamura, M. Sato, Y. Hasegawa andT. Amano,Chem. Lett. (1984) 2059.

  15. K. Okamura, M. Sato andY. Hasegawa,Ceram. Int. 13 (1987) 55.

    Article  CAS  Google Scholar 

  16. M. Sato, Y. Hasegawa andK. Okamura,J. Ceram. Soc. Jpn Inter. Edn. 95 (1987) 937.

    Google Scholar 

  17. K. Kamiya, T. Yoko andM. Bessho,J. Mater. Sci. 22 (1987) 937.

    Article  CAS  Google Scholar 

  18. A. Kato, Y. Ono, S. Kawazoe andI. Mochida,Yogyo-Kyokai-Shi 80 (1972) 114.

    Article  CAS  Google Scholar 

  19. R. C. G. Swann, R. R. Mehta andT. P. Cauge,J. Electrochem. Soc. 114 (1967) 713.

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. The Research Institute for Special Inorganic Materials, Asahi-mura, Kashima-gun, 311-14, Ibaraki-ken, Japan

    Yoshio Hasegawa

  2. The Department of Materials Science and Applied Chemistry, Changsha Institute of Technology, Changsha, Hunan, People’s Republic of China

    Chun-Xiang Feng, Yong-Cai Song & Zi-Lie Tan

Authors
  1. Yoshio Hasegawa
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  2. Chun-Xiang Feng
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  3. Yong-Cai Song
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  4. Zi-Lie Tan
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Hasegawa, Y., Feng, CX., Song, YC. et al. Ceramic fibres from polymer precursor containing Si-O-Ti bonds. J Mater Sci 26, 3657–3664 (1991). https://doi.org/10.1007/BF00557159

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  • DOI: https://doi.org/10.1007/BF00557159

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