Abstract
Toughening mechanisms of a polyamide 6,6/polyphenylene oxide alloy containing an elastomer tested under a slow rate, an impact rate, and a low temperature have been investigated using various microscopy techniques. It is found that the toughening mechanisms of the alloy may change from crazing/shear yielding, to crack bridging/crazing, and to transparticle failure, depending on the testing conditions. Except for the low temperature high strain rate testing condition and in the plane stress region of the crack, the crazing mechanism has been observed in all the conditions we studied. When the testing rate is high, the shear yielding mechanism is suppressed; multiple crazing and particle bridging mechanisms appear to dominate.
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I. M. Ward, “Mechanical Properties of Solid Polymers”, 2nd ed. (Wiley & Sons, New York, 1983).
A. F. Yee andR. A. Pearson,J. Mater. Sci.,21 (1986) 2462;
Idem. ibid. 21 (1986) 2475.
D. S. Parker, H. J. Sue, J. Huang, andA. F. Yee,Polymer,31 (1990) 2267.
A. F. Yee, R. A. Pearson, andH. J. Sue, “Fracture and Toughening Mechanisms in Polymers”, 7th International Conference on Fracture4 (1989) 2739.
H. J. Sue andA. F. Yee,J. Mater. Sci. 24 (1989) 1447.
A. C. Garg andY. W. Mai,Composites Science and Technology 31 (1988) 179.
Idem, “Toughening Mechanisms in Alloys of Rigid Polymers”, 7th International Conference on Deformation, Yield and Fracture of Polymers (Cambridge, England, April 1988).
H. J. Sue,Polym. Eng. Sci.,31 (1991) 275.
Idem, Ph.D. Thesis (The University of Michigan, Ann Arbor, MI, 1988).
S. Y. Hobbs andM. E. J. Dekkers,J. Mater. Sci. 24 (1989) 1316.
S. Kunz-Douglass, P. W. R. Beaumont andM. F. Ashby,J. Mater. Sci. 16 (1981) 2657.
A. J. Kinloch, S. J. Shaw, D. A. Tod, andD. L. Hinston,Polymer 24 (1983) 1341.
H. J. Sue, R. A. Pearson, D. S. Parker, J. Huang, andA. F. Yee,Polymer Preprint 29 (1988) 147.
A. J. Kinloch, “Mechanics and Mechanisms of Fracture of Thermosetting epoxy Polymers”, in “Advances in Polymer Science”, Vol. 72, edited by K. Dusek (Springer-Verlag, Berlin, 1986). p. 45.
M. E. J. Dekkers, S. Y. Hobbs, V. H. Watkins,J. Mater. Sci. 23 (1988) 1225.
T. Kurauchi andT. Ohta,J. Mater. Sci. 19 (1984) 1699.
A. Margolina andS. Wu,Polymer 29 (1988) 2170.
A. S. Holik, R. P. Kambour, S. Y. Hobbs, andD. G. Fink,Microstruct. Sci. 7 (1979) 357.
A. J. Kinloch andJ. G. Williams,J. Mater. Sci. 15 (1980) 987.
R. O. Ritchie andW. Yu, ‘Short Crack Effects in Fatigue: A Consequence of Crack Tip Shielding’ in “Small Fatigue Cracks”, edited by R. O. Ritchie and J. Lankford (TMS-AIME, Warrendale, PA, 1986).
J. G. Williams andJ. M. Hodgkinson,Proc. Roy. Soc. A375 (1981) 231.
C. B. Bucknall, “Toughened Plastics” (Applied Science, London, 1977).
F. J. Guild andR. J. Young,J. Mater. Sci. 24 (1989) 2454.
H. J. Sue andA. F. Yee,Polymer 29 (1988) 1619.
F. Li, A. F. Yee, andJ. Pan, to be published.
R. A. Pearson andA. F. Yee, to be published.
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Sue, H.J., Yee, A.F. Failure mechanisms in alloy of polyamide 6,6/polyphenylene oxide under severe conditions. J Mater Sci 26, 3449–3456 (1991). https://doi.org/10.1007/BF00557130
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DOI: https://doi.org/10.1007/BF00557130