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Polyacrylonitrile-graft-poly(ethylene oxide)

1. Synthesis and characterization of copolymers obtained inN,N-dimethyl formamide solution

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Summary

Graft copolymers of polyacrylonitrile (PAN) and poly(ethylene oxide) (PEO) were synthesized by radical copolymerization of acrylonitrile and methacrylate-headed poly(ethylene oxide) macromonomer. The macromonomer was prepared by reaction of methacryloyl chloride with PEO. The effects of solution concentration, initiator concentration and acrylonitrile/macromonomer molar ratio on the conversion, molecular weight and PEO branch content in the graft copolymer were studied. The graft copolymers were characterized by GPC, FTIR,13C-NMR and Kjeldhal method.

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References

  1. Peng F-M (1985) Acrylonitrile polymers. In: Mark H, Bikales N-M, Overberger C-G (eds) Encyclopedia of Polymer Science and Engineering, Wiley-Interscience, New York (vol 1, pp 426–470)

    Google Scholar 

  2. Lee Y-M, Won K (1990) Polym J 22: 578

    Google Scholar 

  3. Yoshikawa M, Yukoshi T, Sanui K, Ogata N (1984) J Polym Sci Lett 22: 473

    Google Scholar 

  4. Jo W-H, Kim H-J, Kang Y-S (1994) J Appl Polym Sci 51: 529

    Google Scholar 

  5. Kwiatkowski R, Wlochowicz A, Wódka T (1990) Angew Makromol Chem 180: 145

    Google Scholar 

  6. Yan F, Déjardin P, Galin J-C (1990) Polym 31: 736

    Google Scholar 

  7. Schulz G-O, Milkovich R (1982) J Appl Polym Sci 27: 4773

    Google Scholar 

  8. Oliveira C-M-F, Lucas E-F (1990) Polym Bull 24: 363

    Google Scholar 

  9. Annual Book of ASTM Standards (1975) D 1013-70, American Society for Testing and Materials, Philadelphia (part 28, pp 219–220)

  10. Simionescu C, Asandei N, Liga A (1967) Makromol Chem 110: 278

    Google Scholar 

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Authors and Affiliations

  1. Instituto de Macromoléculas Professora Eloisa Mano (IMA), Universidade Federal do Rio de Janeiro, C.P. 68525, Rio de Janeiro, Brazil

    M. Elizabeth F. Garcia & Clara Marize F. Oliveira

  2. Coordenação dos Programas de Pós-Graduação em Engenharia (COPPE), Universidade Federal do Rio de Janeiro, C.P. 68525, Rio de Janeiro, Brazil

    M. Elizabeth F. Garcia & Ronaldo Nobrega

Authors
  1. M. Elizabeth F. Garcia
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  2. Ronaldo Nobrega
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  3. Clara Marize F. Oliveira
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Garcia, M.E.F., Nobrega, R. & Oliveira, C.M.F. Polyacrylonitrile-graft-poly(ethylene oxide). Polymer Bulletin 37, 437–442 (1996). https://doi.org/10.1007/BF00556802

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  • DOI: https://doi.org/10.1007/BF00556802

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