Journal of Materials Science

, Volume 20, Issue 1, pp 149–156 | Cite as

The influence of the various transport properties of the nitriding atmosphere on the formation of reaction-bonded Si3N4

Part 2 Thermal conductivity and thermal diffusivity
  • Heung Kim
  • Chong Hee Kim


The thermal conductivities of nitrogen gas containing various second component gases have been calculated, and the importance of the gaseous phase in thermal conduction during nitridation has been described. Thermal segregations by thermal diffusion inside the nitriding furnace containing the various binary gas mixtures have also been calculated and the influence this effect has on the formation of reaction-bonded Si3N4 is discussed. In N2-H2 and N2-He gas mixtures, nitrogen diffuses down the temperature gradient, leading to a lower concentration of nitrogen and a higher concentration of hydrogen or helium around the silicon compact than expected from the initial composition, whereas in N2-Ar gas mixtures argon diffuses down the temperature gradient, leading to opposite results from the above; such phenomena affect the overall reaction rate and other transport properties. The conclusions obtained have been used in explaining previous experimental results obtained under various nitriding atmospheres.


Thermal Conduction Temperature Gradient Thermal Diffusion Transport Property Opposite Result 
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  1. 1.
    H. Kim andC. H. Kim,J. Mater. Sci. 19 (1984) 141.Google Scholar
  2. 2.
    J. A. Mangels,Amer. Ceram. Soc. Bull. 60 (1981) 613.Google Scholar
  3. 3.
    B. J. Dalgleish, H. M. Jennings andP. L. Pratt,Proc. Brit. Ceram. Soc. 31 (1981) 85.Google Scholar
  4. 4.
    S. Chapman andT. G. Cowling, “The Mathematical Theory of Nonuniform Gases”, 3rd edn. (Cambridge University Press, London, 1970) p. 110–48.Google Scholar
  5. 5.
    J. O. Hirschfelder, C. F. Curtiss andR. B. Bird, “Molecular Theory of Gases and Liquids” (John Wiley, New York, 1954).Google Scholar
  6. 6.
    R. B. Bird, W. F. Stewart andE. N. Lightfoot, “Transport Phenomena” (John Wiley, New York, 1960).Google Scholar
  7. 7.
    A. Atkinson andA. D. Evans,Trans. Brit. Ceram. Soc. 73 (1974) 43.Google Scholar
  8. 8.
    A. Atkinson, A. J. Moulson andE. W. Roberts,J. Amer. Ceram. Soc. 59 (1976) 285.Google Scholar

Copyright information

© Chapman and Hall Ltd. 1985

Authors and Affiliations

  • Heung Kim
    • 1
  • Chong Hee Kim
    • 1
  1. 1.Department of Materials Science and EngineeringKorea Advanced Institute of Science and TechnologyCheongryang, SeoulKorea

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