Abstract
The 10 K emission spectrum of Cs2TeBr6 was measured by recording the fluctuating photon flux. Since this fluctuation, according to the theory, is due to the dynamic coupling of the molecular system to the environment controlling the dissipation of energy, it should depend on the frequency of the emitted photons. By this, the vibrational structure of the transition has been resolved which could not be obtained by usual emission spectroscopy.
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Dedicated to Professor Dr. H. Hartmann, Frankfurt am Main, on the occasion of his seventieth birthday
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Degen, J., Schmidtke, H.H. Vibrational structure of complex compound emission spectra measured by dynamical photon flux fluctuations as predicted in quantum theory of irreversible processes. Theoret. Chim. Acta 67, 33–36 (1985). https://doi.org/10.1007/BF00555019
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DOI: https://doi.org/10.1007/BF00555019