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Chemistry of Heterocyclic Compounds

, Volume 16, Issue 3, pp 222–225 | Cite as

Macroheterocycles. 5. Synthesis of macrocyclic amido esters and amido thioesters on the basis of derivatives of α-hydroxy and α-mercapto acids

  • N. G. Luk'yanenko
  • A. V. Bogat-skii
  • Yu. A. Popkov
Article

Abstract

3,6-Dioxa-4-keto-, 2-benzyl-3,6-dioxa-4-keto-, and 3-oxa-6-thio-5-ketooctanedioic acids were obtained by the reaction of diglycolic acid anhydride with glycolic, β-phenyllactic, and thioglycolic acids. 2,9-Dibenzyl-3,8-dioxa-4,7-diketodecanoic acid was obtained by the reaction of succinyl chloride with β-phenyllactic acid. Eight macrocyclic amido esters and amido thioesters that are new polydentate macrocyclic ligands were synthesized by the reaction of the chlorides of the acids obtained with 3-oxa-1,5-diaminopentane, 3,6-dioxa-1,8-diaminooctane, and 1,4-diaminobutane.

Keywords

Chloride Ester Organic Chemistry Anhydride Acid Anhydride 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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Copyright information

© Plenum Publishing Corporation 1980

Authors and Affiliations

  • N. G. Luk'yanenko
    • 1
  • A. V. Bogat-skii
    • 1
  • Yu. A. Popkov
    • 1
  1. 1.Physicochemical InstituteAcademy of Sciences of the Ukrainian SSROdessa

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