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Chemistry of Heterocyclic Compounds

, Volume 16, Issue 6, pp 658–663 | Cite as

Synthesis and properties of 2-alkyl-5-ethynyltetrazoles

  • S. R. Buzilova
  • V. M. Shul'gina
  • G. A. Gareev
  • L. I. Vereshchagin
Article
  • 54 Downloads

Abstract

2-Alkyl-5-ethynyltetrazoles were synthesized. It is shown that ethynyltetrazoles have a triple bond with increased electrophilicity. They readily add aliphatic alcohols and amines and undergo aminomethylation, the Iotsich reaction, oxidative dimerization, and the cycloaddition of azides. 1-Phenyl-3-tetrazolyl-2-propyne, which has the properties of α-acetylenic ketones, was obtained by selective oxidation of tetrazolylethynylcarbinol.

Keywords

Oxidation Alcohol Organic Chemistry Ketone Azide 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1980

Authors and Affiliations

  • S. R. Buzilova
    • 1
  • V. M. Shul'gina
    • 1
  • G. A. Gareev
    • 1
  • L. I. Vereshchagin
    • 1
  1. 1.Institute of Petrochemical and Coal-Chemical SynthesisIrkutsk State UniversityAngarsk

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