Chemistry of Heterocyclic Compounds

, Volume 16, Issue 6, pp 653–657 | Cite as

Derivatives of 1,2,5,6,9,12-hexaazacyclotetradecatetraene and 1,2,5,6,9,14-hexaazacyclohexadecahexaene based on 2,3-dihydrazinoquinoxaline

  • V. M. Dziomko
  • M. N. Stopnikova
  • Yu. S. Ryabokobylko
Article
  • 23 Downloads

Abstract

A bis(hydrazone) was synthesized by the reaction of 2,3-dihydrazinoquinoxaline with 3-methyl-1-phenyl-1H-pyrazole-4,5-dione. Treatment of the bis(hydrazone) with POC13 and Et3N gave a dichloro diazo compound, from which macrocyclic metal chelates, viz., derivatives of 1,2,5,6,9,12-hexaazacyclotetradecatetraene and 1,2,5,6,9,14-hexaazacyclohexadecahexaene, were obtained by reaction with diamines in dimethylformamide in the presence of Pd(II) and Ni(II)salts.

Keywords

Organic Chemistry Diamine Dione Dimethylformamide Hydrazone 

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Copyright information

© Plenum Publishing Corporation 1980

Authors and Affiliations

  • V. M. Dziomko
    • 1
  • M. N. Stopnikova
    • 1
  • Yu. S. Ryabokobylko
    • 1
  1. 1.All Union Scientific-Research Institute of Chemical Reagents and Ultrapure Chemical SubstancesMoscow

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