Abstract
Conventional and high resolution transmission electron microscopy performed in this study provides some detailed microstructural information of a polyacrylonitrile (PAN) fibremesophase pitch matrix carbon-carbon composite which has not been published in open literature. The PAN fibre in this composite possesses a turbostratic structure throughout the fibre. The structure of the mesophase pitch matrix is graphitic and anisotropic. Near-fibre matrix crystallites are aligned roughly parallel to the fibre surface, exhibiting a flow-type morphology. The fibre-matrix interface in this composite is microfissured. Numerous microcracks exist both within the matrix and along partially bonded interfaces. The irregularly shaped interfacial microcracks readily expose the fibre surface topography. Microcracks within the matrix are formed between, and parallel to, the basal planes of the graphitic platelets. Such submicron-sized matrix cracks appear smaller and denser near the fibre-matrix interface.
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References
A. Oberlin, in Proceedings of the Third Materials Technology Center's Conference on Solid Carbon Materials: Production and Properties, Carbondale, IL (Materials Technology Center, Carbondale, IL) p. 163.
D. Crawford andD. J. Johnson,J. Microscopy 94 (1971) 51.
S. C. Bennett andD. J. Johnson,Carbon 17 (1979) 25.
I. Mochida, I. Ito, Y. Korai, H. Fujitsu andK. Takeshita,Carbon 19 (1981) 457.
D. J. Johnson, D. Crawford andB. F. Jones,J. Mater. Sci. 8 (1973) 286.
X. Bourrat, E. J. Roche andJ. G. Lavin,Carbon 28 (1990) 236.
H. Marsh,Fuel 52 (1973) 205.
M. Shiraishi, G. Terriere andA. Oberlin,J. Mater. Sci. 13 (1978) 702.
D. Auguie, M. Oberlin, A. Oberlin andP. Hyvernat,Carbon 18 (1980) 337.
H. Marsh andD. Crawford,Carbon 22 (1984) 413.
S. DeFonton, A. Oberlin andM. Inagaki,J. Mater. Sci. 15 (1980) 909.
M. Inagaki, A. Oberlin andS. Defonton,High Temp. High Pressures 9 (1977) 453.
J. Goma andA. Oberlin,Carbon 23 (1985) 85.
J. N. Rouzaud andA. Oberlin,Thin Solid Films 105 (1983) 75.
M. Huttepain andA. Oberlin,Carbon 28 (1990) 103.
P. Ehrburger andJ. Lahaye,Carbon 19 (1981) 1.
J. Don andC. P. Ju,Mater. Sci. Engng A124 (1990) 259.
E. Fitzer, W. Hüttner andL. M. Manocha,Carbon 18 (1980) 291.
S. M. Oh andJ. Y. Lee,Carbon 26 (1988) 769.
J. E. Zimmer andJ. L. White,Carbon 21 (1983) 323.
J. H. Cranmer, I. G. Platzker, L. H. Peebles andD. R. Uhlman,Carbon 21 (1983) 201.
R. A. Meyer andS. R. Gyetvay, in “Petroleum derived carbons”, ACS Symposium Vol. 303, edited by J. D. Bacha, J. W. Newman, and J. L. White (American Chemical Society, Washington, D.C. 1986) p. 380.
N. Murdie, J. Don, W. Kowbel, P. Shpik andM. A. Wright, Personal Communications.
C. P. Ju, Unpublished research.
L. H. Peebles Jr., R. A. Meyer andJ. Jortner, in Proceedings of Second International Conference on Composite Interfaces (ICCI-1), Cleveland, June 1988, edited by H. Ishida (Elsevier, New York) p. 1.
J. Jortner,Carbon 24 (1986) 603.
M. A. Forrest andH. Marsh,J. Mater. Sci. 18 (1983) 973.
S. Ragan andH. Marsh,J. Mater. Sci. 18 (1983) 3712.
K. Y. Sohn, Seh-Min Oh andJai-Young Lee,Carbon 26 (1988) 157.
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Ju, C.P., Don, J. & Tlomak, P. Transmission electron microscopic study of three-dimensional polyacrylonitrile fibre-mesophase pitch matrix carbon-carbon composite. J Mater Sci 26, 6753–6758 (1991). https://doi.org/10.1007/BF00553702
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DOI: https://doi.org/10.1007/BF00553702