Skip to main content
Log in

Interaction of Fecralloy with sodium disilicate glass

  • Papers
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

Interactions of sodium disilicate glass with Fecralloy, Fe-6Cr-4Al-0.25Y, have been analysed in terms of the Pask chemical equilibrium theory. Sessile drops assumed contact angles of 38 to 47‡ at 900 to 1100‡C on polished substrates following interactions that led to significant weight losses. Up to 7% of aluminium and much smaller amounts of iron, chromium manganese and yttrium were taken into the glass. On pre-oxidized substrates, coated with alumina, near-perfect wetting was achieved but once more aluminium was taken into the glass and weight losses suffered. These data can be interpreted as resulting from redox reactions between the aluminium in the alloy and the sodium monoxide in the glass.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. J. A. Pask andR. M. Fulrath,J. Amer. Ceram. Soc. 45 (1962) 592.

    Article  CAS  Google Scholar 

  2. J. A. Pask, in “Modern Aspects of the Vitreous State”, Vol. 3, edited by J. D. McKenzie (Butterworths, London, 1964) p. 1.

    Google Scholar 

  3. J. A. Pask andM. P. Borom, “Physical Chemistry of Glass-Metal Interfaces”, UCRL-118/6 REV (University of California, 1965).

  4. B. W. King, H. P. Tripp andW. H. Duckworth,J. Amer. Ceram. Soc. 42 (1959) 504.

    Article  CAS  Google Scholar 

  5. V. K. Bhat andC. R. Manning,ibid. 56 (1973) 455.

    Article  CAS  Google Scholar 

  6. L. H. Van Vlack,Metals. Eng. Q. (Nov. 1965) 7.

  7. J. V. Smith andS. W. Bailey,Acta Crystallogr. 16 (1963) 801.

    Article  CAS  Google Scholar 

  8. R. W. Jones,Fortschr. Deutschen Keramischen Gesellschaft 1 (1985) 99.

    Google Scholar 

  9. A. P. Tomsia andJ. A. Pask,J. Amer. Ceram. Soc. 69 (1981) 523.

    Article  Google Scholar 

  10. R. Hultgren, P. D. Desai andD. T. Hawkins, “Selected Value of Thermodynamic Properties of Binary Alloys” (ASM, Metals Park, Ohio, 1973).

    Google Scholar 

  11. C. T. Lynch (ed.), “Handbook of Materials Science”, Vol. 2 (CRC Press, Cleveland, 1975) p. 339.

    Google Scholar 

  12. O. V. Mazurin, M. V. Streltsina andT. P. Shvaiko-Shvaikovskaya, “Handbook of Glass Data, Part A” (Elsevier, 1983) p. 169.

  13. A. P. Tomsia, Z. Feipeng andJ. A. Pask,Bull. Amer. Ceram. Soc. 63 (3) (1984) 473.

    Google Scholar 

  14. A. P. Tomsia, private communication (1984).

  15. E. A. Brandes (ed.), “Metals Reference Book”, 6th Edn (Butterworths, London, 1983) p. 8.

    Google Scholar 

  16. L. Pauling, “The Nature of the Chemical Bond” 2nd edn. (Cornell University Press, 1939) p. 98.

  17. H. O. Pritchard andH. A. S. Kinner,Chem. Rev. 55 (1955) 745.

    Article  CAS  Google Scholar 

  18. A. E. Paladino andW. D. Kingery,Chem. Phys. 37 (1962) 957.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Nicholas, M.G. Interaction of Fecralloy with sodium disilicate glass. J Mater Sci 21, 3292–3296 (1986). https://doi.org/10.1007/BF00553372

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00553372

Keywords

Navigation