Abstract
A theory is proposed for solid-state growth of the chemical compound layers at the interface between two elementary substances one of which is solid at the given temperature while the other may be solid, liquid or gaseous. Not only the rates of diffusional transport of the reacting species through the growing layers but also the rates of chemical reactions taking place at the interfaces between the phases involved in the interaction are taken into account. This theory seems to be more consistent with the available experimental data than the existing “diffusional” theory.
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Dybkov, V.I. Reaction diffusion in heterogeneous binary systems. J Mater Sci 21, 3078–3084 (1986). https://doi.org/10.1007/BF00553339
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DOI: https://doi.org/10.1007/BF00553339