Abstract
The isothermal transformation behaviour of the metallic glass Fe40Ni40P14B6 between 320 and 400° C is described. Crystallization occurs by a eutectic mechanism to form Fe-Ni austenite and a body-centred tetragonal phase which is isomorphous with Fe3P and Ni3P. The eutectic crystals have a barrel shape such that the c-axis of the tetragonal phase is parallel to the barrel axis. The orientation relationship between the two phases is 〈1 1 0〉T ∥ 〈1 1 0〉γ and 〈0 0 1〉T ∥ 〈1 1 2〉γ. The austenite phase contains (1 1 1) twins.
Similar content being viewed by others
References
W. Klement, R. H. Willens and P. Duwez, Nature 187 (1960) 869.
“Metallic Glasses”, ASM Seminar Series (ASM, Ohio, 1978).
“Rapidly Quenched Metals III”, Proceedings of the 3rd International Conference on Rapidly Quenched Metals, Brighton 2–7 July 1978 (The Metals Society, London, 1978).
M. G. Scott, ibid“, Vol. I, p. 198.
H. S. Chen, J. Appl. Phys. 49 (1978) 3289.
T. Egami, Mat. Res. Bull. 13 (1978) 557.
H. H. Liebermann, C. D. Graham and P. J. Flanders, I.E.E.E. Trans. Mag. MAG 13 (1977) 1541.
C. D. Graham, T. Egami, R. S. Williams and Y. Takei, AIP Conf. Proc. 29 (1976) 218.
F. E. Luborsky` and J. L. Walter, J. Appl. Phys. 47 (1976) 3648.
M. G. Scott, J. Mater. Sci. 13 (1978) 291.
F. E. Luborsky, Mater. Sci. Eng. 28 (1977) 139.
C. Antonione, L. Battexxati, A. Lucci, G. Riontino and G. Venturello, Scripta Met. 12 (1978) 1011.
J. L. Walter, S. F. Bartram and R. R. Russell, Met. Trans. 9A (1978) 803.
D. G. Ast and D. Krenitsky, Mater. Sci. Eng. 23 (1976) 241.
U. Herold and U. Koster, “Rapidly Quenched Metals III”, Proceedings of the 3rd International Conference, Brighton, 2–7 July 1978 (The Metals Society, London, 1978) p. 281.
J. Burke, “Kinetics of Phase Transformations in Metals” (Pergamon, Oxford, 1965) p. 192.
J. W. Christian, “The Theory of Transformations in Metals and Alloys” (Pergamon, Oxford, 1965) p. 489.
W. B. Pearson “Handbook of Lattice Spacings and Structures of Metals and Alloys” (Pergamon, Oxford, 1958).
U. Koster and U. Herold, Scripta Met. 12 (1978) 75.
P. G. Boswell and G. A. Chadwick, ibid 10 (1976) 509.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Watanabe, T., Scott, M. The crystallization of the amorphous alloy Fe40Ni40P14B6 . J Mater Sci 15, 1131–1139 (1980). https://doi.org/10.1007/BF00551801
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00551801