Abstract
It was shown that oxidative dehydrogenation with primary formation of C=C double bonds and then C=C conjugated bonds is the basic chemical reaction in the early stages of thermal stabilization of PAN fibres. A hypothesis was advanced concerning the nature of the appearance of oxygen-containing functional groups. A correlation was found between the amount of oxygen added to the fibre and its density.
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Translated from Khimicheskie Volokna, No. 1, pp. 10–13, January–February, 1995.
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Azarova, M.T., Bondarenko, V.M. & Savchenko, G.I. Thermal transformations of polyacrylonitrile fibres with deep degrees of conversion. Fibre Chem 27, 5–9 (1995). https://doi.org/10.1007/BF00551520
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DOI: https://doi.org/10.1007/BF00551520