Skip to main content
Log in

Differential thermal analysis, structure and switching of thin chalcogenide films

  • Papers
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

Differential thermal analysis (DTA) and electron diffraction techniques have been used to characterize thin chalcogenide alloy films by comparison with the properties of bulk alloys from which they were deposited. It is shown that the DTA technique is a valuable adjunct to structural studies on thin films since it helps to differentiate between the two non-crystalline states, amorphous and vitreous or glassy. It is observed that the former does not produce reproducible reversible threshold switching from a high impedance to a low impedance state whereas the latter does.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. N. Onodera, H. Suga, and S. Seki, J. Non-Cryst. Sol. 1 (1969) 331.

    Google Scholar 

  2. H. S. Chen and C. E. Miller, Rev. Sci. Inst. 41 (1970) 1237.

    Google Scholar 

  3. S. Iizima, M. Sugi, M. Kikuchi, and K. Tanaka, Solid State Comms. 8 (1970) 153.

    Google Scholar 

  4. C. B. Thomas, A. Fray, and J. R. Bosnell, Phil. Mag. (in press).

  5. See for example J. Non-Cryst. Solids 2 and 4 (1970).

  6. J. A. Savage, J. Mater. Sci. 6 (1971) 964.

    Google Scholar 

  7. J. Dixmier and A. Guinier, Proc. Int. Conf. on Metastable Alloys, Fizika 2 Suppl. 2 (1970) 9.1.

    Google Scholar 

  8. B. G. Bagley, H. S. Chen, and D. Turnbull, Mat. Res. Bull. 3 (1968) 159.

    Google Scholar 

  9. J. R. Bosnell, Thin Solid Films 3 (1969) 233.

    Google Scholar 

  10. B. C. Giessen and E. W. Willens, “Phase Diagrams” in Materials Science and Technology, ed. A. M. Alper, vol. 3 (Academic Press, New York and London, 1970) p. 129.

    Google Scholar 

  11. J. R. Bosnell, MRC Sputtering School, Brighton (1971).

  12. M. L. Theye, Optics Comms. 2 (1970) 329.

    Google Scholar 

  13. K. L. Chopra and S. K. Bahl, Phys. Rev. 131 (1970) 2545.

    Google Scholar 

  14. J. R. Bosnell and U. C. Voisey, Thin Solid Films 6 (1970) 151.

    Google Scholar 

  15. H. S. Chen and D. Turnbull, J. Appl. Phys. 40 (1969) 4114.

    Google Scholar 

  16. H. Fritzche, J. Non-Cryst. Solids 6 (1971) 49.

    Google Scholar 

  17. C. T. Mognihan and U. E. Sahnans, J. Amer. Ceram. Sac. 54 (1971) 136.

    Google Scholar 

  18. J. Dresner and G. B. Stringfellow, J. Phys. Chem. Solids 29 (1968) 303.

    Google Scholar 

  19. S. A. Keneman, Appl. Phys. Letts. 19 (1971) 205.

    Google Scholar 

  20. S. Marino, Jap J. Appl. Phys. (1968) 1434; S. Tsuchihashi and Y. Kawansioto, J. Non-Cryst. Solids 5 (1971) 286.

  21. M. D. Coults and E. R. Levin, J. Appl. Phys. 38 (1967) 4039.

    Google Scholar 

  22. S. A. Demobovskii, I. A. Kirilenko, and A. S. Khvorostenko, Russian J. Inorg. Chem. 13 (1968) 768.

    Google Scholar 

  23. T. Takamori, R. Roy, and G. J. McCarthy, Mat. Res. Bull. 5 (1970) 529.

    Google Scholar 

  24. Idem, J. Appl. Phys. 42 (1971) 2577.

    Google Scholar 

  25. S. R. Ovshinsky, US Patent 3271591 (Sept. 1966).

  26. R. Pinto and K. V. Ramanathan, Appl. Phys. Letts. 19 (1971) 221.

    Google Scholar 

  27. R. C. De Vekey and A. J. Majumdar, Nature 225 (1970) 172.

    Google Scholar 

  28. L. P. Andreeva and M. V. Karpenko, Fiz Tverdogo, Tela 13 (1971) 2122.

    Google Scholar 

  29. J. M. Stevels, J. Non-Cryst. Solids 6 (1971) 307.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bosnell, J.R., Savage, J.A. Differential thermal analysis, structure and switching of thin chalcogenide films. J Mater Sci 7, 1235–1243 (1972). https://doi.org/10.1007/BF00550688

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00550688

Keywords

Navigation