Abstract
The degradation of mechanical properties in nylon 6 films due to both oxidative and non-oxidative photodegradation is studied. It is shown that in a non-oxygen environment the rate of degradation is enhanced with rising temperature due to increases in quantum yield. Experimental results obtained on specimens exposed to natural weathering are found to be difficult to relate to those obtained by accelerated ageing. It is proposed and proven that the specific energy absorption in a tensile test (W p) is an effective parameter for characterizing photodegradation in nylon.
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J. W. S. Hearle and B. Lomas, J. Appl. Polymer Sci. 21 (1977) 1103.
R. A. Coleman and W. H. Peacock, Textile Res. J. 28 (1958) 784.
R. F. Moore, Polymer 4 (1963) 493.
W. Schnabel and J. Kiwi, in “Aspects of Degradation and Stabilization of Polymers”, edited by H. H. G. Jellinek (Elsevier, Amsterdam, Oxford and New York, 1978) pp. 195–246.
G. A. George and N. McM. Browne, “Non-destructive evaluation of the degradation of nylon 6,6 parachute materials”, Materials Research Laboratories, Department of Defence, Melbourne, Australia, Report No. MRL-R-691, June 1977.
G. Marom, E. Harel and J. Rosner, J. Appl. Polymer Sci. 21 (1977) 1629.
G. E. Anderton and L. R. G. Treloar, J. Mater. Sci. 6 (1971) 562.
B. Cotterell and J. K. Reddel, Inst. J. Fract. 13 (1977) 267.
Y. W. Mai and B. Cotterell, J. Mater. Sci. 15 (1980) 2296.
G. T. Hahn, P. K. Dai and A. R. Rosenfeld, Proceedings of the 1st International Conference on Fracture, Vol. 1 (1965) 229.
J. E. Guillet, in “Degradation and Stabilization of Polymers”, edited by G. Genskens (Applied Science Publishers, London, 1975) pp. 181–98.
G. L. A. Sims, J. Mater. Sci. 10 (1975) 647.
A. G. Atkins and Y. W. Mai, Int. J. Fract. 12 (1976) 923.
F. J. Guild, A. G. Atkins and B. Harris, J. Mater. Sci. 13 (1978) 2295.
O. F. Yap, Int. J. Fract. 15 (1979) R209.
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Mai, Y.W., Head, D.R., Cotterell, B. et al. Mechanical properties of nylon 6 subjected to photodegradation. J Mater Sci 15, 3057–3065 (1980). https://doi.org/10.1007/BF00550376
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DOI: https://doi.org/10.1007/BF00550376