Abstract
Thermoluminescent characteristics of Al2O3 and MgO single crystal samples obtained from several sources have been determined after X-ray and ultra-violet irradiation. The glow peak spectrum above room temperature, the emission spectrum, the impurity content and distribution and the activation parameters for the observed glow peaks are reported. Czochralski-grown Al2O3 samples indicate a major glow peak, the position of which shifts to lower temperatures with increasing dose, an observation with interesting implications in thermoluminescent radiation dosimetry. MgO also has characteristics which could be useful in dosimetry, especially in the ultra-violet region. Activation parameter comparisons are made for the observed glow peaks in Al2O3 and MgO and in LiF (TLD-100). After considering a number of theoretical and experimental problems and uncertainties, it is concluded that determinations of activation parameters are less meaningful than observations of other thermoluminescent characteristics in the understanding of thermoluminescent behaviour.
Similar content being viewed by others
References
F. H. Attix, “Luminescence Dosimetry” (USAEC, 1967), available from CFSTI as Conf 6506 37.
J. R. Cameron, N. Suntharalingam, and G. N. Kenney, “Luminescence Dosimetry” (University of Wisconsin Press, London, 1968).
M. J. Rossiter, D. B. Rees-Evans, S. C. Ellis, and J. M. Griffiths, J. Phys. D: Appl. Phys. 4 (1971) 1245.
L. A. Dewerd and T. G. Stoebe, Proc. Third Int'l. Conf. Luminescence Dosimetry, Riso, Denmark (1971).
G. A. Dussel and R. H. Bube, Phys. Rev. 155 (1967) 764.
P. Kelly and P. Braunlich, Phys. Rev. B1 (1970) 1587.
I. J. Saunders, J. Phys. C: Solid State Phys. 2 (1969) 2181.
H. S. Parker and C. H. Harding, J. Amer. Ceram. Soc. 53 (1970) 583.
D. W. Cooke and D. C. Sutherland, paper presented at the Southeastern section of the American Physical Society, Gainsville, Florida, USA (1969).
J. B. Van Tright and B. A. M. Van Der Kraay, J. Phys. Chem. Solids 30 (1969) 1629.
A. F. Gabrysh, J. M. Kennedy, H. Eyring, and V. R. Johnson, Phys. Rev. 131 (1963) 1543.
W. G. Buckman, D. C. Sutherland, and D. W. Cooke, Proceedings of the Fourth Annual Midyear Topical Symposium of the National Health Physics Society (1970) p. 407.
M. Srinivasan and T. G. Stoebe, J. Appl. Phys. 41 (1970) 3726.
J. E. Wertz, L. C. Hall, J. Helgeson, C. C. Chao, and W. S. Dykoski, “Interaction of Radiation with Solids” (Plenum Press, New York, 1967) p. 617.
B. Thomas and E. Houston, Brit. J. Appl. Phys. 15 (1964) 953.
R. L. Hansler and W. G. Segelken, J. Phys. Chem. Solids 13 (1960) 124.
W. M. Ziniker, J. K. Merrow and J. I. Mueller, J. Phys. Chem. Solids 33 (1972) 1619.
J. T. Randall and M. H. F. Wilkins, Proc. R. Soc. A. 184 (1945) 366.
G. F. J. Garlick and A. F. Gibson, Proc. Phys. Soc. 60 (1948) 574.
P. R. Moran and E. B. Podgorsak, USAEC Progress Report COO-1105-164 under contract AT(11-1) 1105 (1971).
P. R. Moran and J. R. Cameron, Proc. Third Int'l. Conf. Luminescence Dosimetry, Riso, Denmark (1971).
R. Chen, J. Appl. Phys. 40 (1969) 570.
P. J. Kelly and M. J. Laubitz, Can. J. Phys. 45 (1967) 311.
T. M. Searle and A. M. Glass, J. Phys. Chem. Solids 29 (1968) 609.
E. T. Rodine and P. L. Land, Phys. Rev. B4 (1971) 2701.
D. W. Zimmerman, C. R. Rhyner, and J. R. Cameron, Health Physics 12 (1966) 525.
J. H. Jackson and A. M. Harris, J. Phys. C: Solid State Phys. 3 (1970) 1967.
L. D. Miller and R. H. Bube, J. Appl. Phys. 41 (1970) 3687.
L. I. Grosswiener, ibid 24 (1953) 1306.
C. B. Luschik, Dokl. Acad. Nauk. SSSR 101 (1955) 641.
E. Yamaka, Phys. Rev. 96 (1954) 293.
H. G. Hecht and E. D. Taylor, J. Phys. Chem. Solids 28 (1967) 1599.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Ziniker, W.M., Rusin, J.M. & Stoebe, T.G. Thermoluminescence and activation energies in Al2O3, MgO and LiF (TLD-100). J Mater Sci 8, 407–414 (1973). https://doi.org/10.1007/BF00550162
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00550162