Abstract
The surface of the catalyst, Ln2Ti2O7 where Ln=Y, Sm, Gd and Tb was analysed by X-ray photoelectron spectroscopy. Terbium is found to be present in 3+ and 4+ states while Y, Sm and Gd are present in the 3+ state. The catalytic activity of these oxides was tested using decomposition of N2O as the test reaction and the catalytic activity was correlated to the surface properties.
Similar content being viewed by others
References
J. B. Goodenough and R. N. Castellono, J. Solid State Chem. 44 (1982) 108.
J. H. H. Termaat, M. P. Van Dijk, G. Roelofs, H. Bosch, G. M. H. Van De Velde, P. J. Gellings and A. J. Burggraaf, Mater. Res. Bull. 19 (1984) 1271.
S. J. Korf, H. J. A. Koopmans, B. C. Lippens Jr., A. J. Burggraaf and P. J. Gellings, J. Chem. Soc. Faraday Trans. I 83 (1987) 1485.
T. R. Felthouse, J. Amer. Chem. Soc. 109 (1987) 7566.
H. S. Horowitz, J. M. Longo and H. H. Horowitz, J. Electrochem. Soc. 130 (1983) 1851.
J. Christopher and C. S. Swamy, Proceedings of 9th National Symposium on Catalysts (Tata McGraw Hill, New York, 1989) p. OS.54.
L. H. Brixner, Inorg. Chem. 3 (1964) 1065.
M. A. Subramanian, G. Aravamudan and G. V. Subba Rao, Prog. Solid Stat Chem. 15 (1983) 55.
P. Selvam, B. Viswanathan, C. S. Swamy and V. Srinivasan, Proceedings 8th National Symposium on Catalysts (Edited by S. R. Naidu and B. K. Banerjee) (PDIL, Sindri, 1987) Vol. 1 (1987) 306.
P. Selvam, B. Viswanathan, C. S. Swamy and V. Srinivasan, Indian J. Technol. 25 (1987) 639.
H. Chermette, D. Pertosa and F. M. Michelcalendini, Chem. Phys. Lett. 69 (1980) 240.
S. K. Sen, J. Riga and J. Verbist, Chem. Phys. Lett. 39 (1976) 560.
M. E. Levin, M. Salmeron, A. T. Bell and G. A. Somorjai, Surf. Sci. 195 (1988) 429.
C. N. Sayers and N. R. Armstrong, ibid. 77 (1978) 301.
K. S. Kim and N. Winograd, Chem. Phys. Lett. 31 (1975) 312.
A. J. Signorelli and R. G. Hayes, Phys. Rev B 8 (1973) 81.
C. D. Wagner, in “Practical surface analysis by Auger and Photoelectron Spectroscopy”, edited by D. Briggs and M. P. Seah (John Wiley, New York, 1983).
D. D. Sharma, P. Vishnu Kamath and C. N. R. Rao, Chem. Phys. 73 (1983) 71.
P. Burroughs, A. Hammett, A. F. Orchard and G. Thronton, J. Chem. Soc. Dalton Trans. 17 (1976) 1686.
G. Dufour, R. C. Karnatak, J. M. Mariot and C. Bonnelle, Chem. Phys. Lett. 42 (1976) 433.
G. Vander Lean, J. C. Fuggle, M. P. Van Dijk, A. J. Burggraaf, J. M. Esteva and R. Karnatak, J. Phys. Chem. Solids 47 (1986) 413.
L. M. Moroney, R. S. Smart and M. V. Roberts, J. Chem. Soc. Faraday Trans. I. 79 (1983) 1769.
M. S. Hegde and M. Ayyoob, Surf. Sci. 173 (1986) 2635.
G. Nagasubramanian, M. V. C. Sastri and B. Viswanathan, J. Indian Chem. Soc. 56 (1979) 158.
B. Viswanathan, Indian Chemical. Manufacturer, 9 (1980) 1.
Idem., Chemical Age of India 29 (1978) 743.
A. Boronicolos and J. C. Vickerman, J. Catal. 100 (1986) 59.
G. Nagasubramanian, B. Viswanathan and M. V. C. Sastri, Indian J. Chem. 16A (1978) 642.
C. J. Powell and P. E. Larson, Appl. Surf. Sci. 1 (1978) 186.
A. R. Miedema, Z. Metallkde 69 (1978) 287.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Christopher, J., Swamy, C.S. Surface characterization and catalytic activity of Ln2Ti2O7 (Ln=Y, Sm, Gd and Tb). J Mater Sci 26, 4966–4970 (1991). https://doi.org/10.1007/BF00549878
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/BF00549878