Abstract
Splat-quenched Cd-Zn alloys having less than ≃35 at % Zn and less than ≃15 at % Cd solidify without solute partitioning at the highest cooling rates that can be attained using a room-temperature substrate. Lower cooling rates yield fine-grained microduplex structures possibly resulting from interdendritic precipitation or from the independent nucleation and growth of the terminal Cd and Zn phases. A further reduction in the cooling rate gives a transition from microduplex to lamellar eutectic solidifcation in the eutectic (Cd-26.5 at % Zn) alloy.
Similar content being viewed by others
References
P. Duwez, R. H. Willens and W. Klement, J. Appl. Phys. 31 (1960) 1136.
P. Duwez, Prog. Solid State Chem. 3 (1967) 377.
J. C. Baker and J. W. Cahn, Acta Met. 17 (1969) 575.
B. C. Giessen, “The Crystal Chemistry of Metals and Alloys” (Interscience, New York, 1972) p. 287.
H. Jones, Rep. Prog. Phys. 36 (1973) 1425.
T. B. Massalski, L. F. Vassamillet and Y. Bienvenu, Acta Met. 21 (1973) 649.
P. Duwez and R. H. Willens, Trans. Met. Soc. AIME 227 (1963) 362.
W. B. Pearson, “Handbook of Lattice Spacings and Structures of Metals and Alloys” (Pergamon Press, London, 1958).
R. T. Southin and G. A. Chadwick, Acta Met. 26 (1978) 223.
A. Moore and R. Elliot, “The Solidification of Metals” (Iron and Steel Institute, London, 1967) p. 167.
T. Yamamoto and H. Nishizawa, Phys. Stat. Sol. 28A (1975) 237.
P. G. Boswell and G. A. Chadwick, J. Mater. Sci. 12 (1977) 1879.
Idem, Scripta Met. 11 (1977) 459.
M. J. Burden and H. Jones, J. Inst. Metals 98 (1970) 249.
T. Z. Kattamis and M. C. Flemings, Met. Trans. 1 (1970) 1449.
W. A. Tiller, “Liquid Metals and Solidification” (American Society for Metals, Cleveland, 1957) p. 276.
L. M. Sergeev, Tsvet. Metally. 14 (1974) 67.
M. F. Chell and W. H. Kerr, Met. Trans. 3 (1972) 2002.
C. Zener, Trans. AIME 167 (1946) 550.
H. Fredriksson, Met. Trans. 6A (1975) 1658.
P. Ramachandrarao, M. G. Scott and G. A. Chadwick, Phil. Mag. 25 (1972) 961.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Boswell, P.G., Chadwick, G.A. The structure of splat-quenched cadmium-zinc alloys. J Mater Sci 14, 1269–1279 (1979). https://doi.org/10.1007/BF00549297
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00549297