Abstract
Santiago is a city of over 4.5 million inhabitants and about 415000 motor vehicles using leaded gasoline. Twenty-four-hour samples were taken of total and fractionated particulate matter using a low-volume system and two Andersen cascade impactors, between 1978 and 1989 at different sites of the city of Santiago. Lead concentrations were determined by atomic absorption spectrophotometry. The results show that Pb concentrations vary greatly depending on the site selected. Higher values are always detected near the city center. An annual variation with the highest value during the autumn-winter period (May–July) is clearly observed. Lead concentrations versus size are clearly biased to particles smaller than 2 µm. A correlation is observed between Pb concentrations and the suspended particulate matter under 3 µm at different sites of the city. The curves of Pb concentration versus size of the aerosols emitted by the gas exhaust of motor vehicles using leaded gasoline are similar to those of the atmospheric aerosols.
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AIEA: 1978, Technical Report, Serie No. 179, Vienna.
Boiteau, F.L., Viala, A., Metayer, C., Grimaldi, F., Corneteau, H., Mola, P., Pineau, A. and Gouezzo, F.: 1983, ‘Taux de Pb et de Cd dans les poussières recueillies à l'intérieur des habitations dans neuf regions de France’, VIième Congrèss Mondial pour la Qualité de l'Air. Proceeds. 2, 233–240.
Bravo, H.A., Perrin, F.G., Sosa, R.E. and Torres, R.J.: 1989, ‘Result of an Air Pollution Strategy (Lead Reduction in Gasoline) on the Air Quality of Mexico City’, Man and His Ecosystem, Proceedings of the VIII Clean Air Congress, 4, 31–37.
Buerki, P.R., Gaelli, B.C. and Nyffeler, Urs.P.: 1989, ‘Size-Resolved Trace Metal Characterization of Aerosols Emitted by Four Important Source Types in Switzerland’, Atmosph. Environ. 23, 1659–1668.
Byrd, D.S., Gilmore, J.T. and Lea, R.H.: 1983, ‘Effect of Decreased Use of Lead in Gasoline on the Soil of a Highway’, Environ. Sci. and Technol. 17, 121–123.
Cass, G.R. and McRae, G.J.: 1983, ‘Source-Receptor Reconciliation of Routine Air Monitoring Data for Trace Metals: An Emission Inventory Assisted Approach’, Environ. Sci. and Technol. 17, 129–139.
Dzubay, T.G., Stevens, R.K., Gordon, G.E., Olmez, I., Sheffield, A.E. and Courtney, N.J.: 1988, ‘A Composite Receptor Method Applied to Philadelphia Aerosol’, Environ. Science and Technol. 22, 46–52.
Eisenreich, S.J., Metzer, N.A. and Urban, N.R.: 1986, ‘Response of Atmospheric Lead to Decreased Use of Lead in Gasoline’, Environ. Sci. and Technol. 20, 171–174.
De Regge, P., Lievens, F., Delespaul, I. and Monsecour, M.: 1978, Proceedings, Symposium, Vienna.
Gauley, J.T. and Springer, G.S. (Eds.): 1974, ‘Physical and Chemical Characteristics of Particulates in Spark Ignition Engine Exhaust’, Environ. Science and Technol. 8, 340–347.
Gällipurghart, B.: 1990, ‘Surveillance des métaux lourds au moyen de l'analyse des mousses’, Pollution atmosphérique 126, 210–211.
Huntzicker, J.J., Friedlander, S.K. and Davidson, C.I.: 1975, ‘Material Balance for Automobile-Emitted Lead in Los Angeles Basin’, Environ. Science and Technol. 9, 448–457.
Hofscheuder, P. and Harssema, H.: 1983, ‘Emission, Dispersion and Deposition of Automotive Pollution’, VIième Congrèss Mondial pour la Qualité de l'Air. Proceeds. 4, 113–119.
Infante, R. and Acosta, F.L.: 1991, ‘Size Distribution of Trace Metals in Ponce, Puerto Rico Air Particulate Matter’, Atmospheric Environment 25B, 121–131.
Kleinman, M.T.: 1980, ‘Identifying and Estimating the Relative Importance of Sources of Airborne Particulates’, Environ. Sci. and Technol. 14, 62–65.
Lee, R.E., Patterson, R.K., Crider, W.R. and Watgman, J.: 1971, Atmosph. Environ. 5, 225–237.
Perkins, H.C.: 1974, Air Pollution, Intern. Student Ed., McGraw Hill, Kogokusha, Ltda, Tokyo.
Petrilli, F.L., Orlando, P., Perdelli, F., Franco, Y. and Nante, N.: 1983, ‘Exposition to Heavy Metals of an Industrial Area Resident Population’, VIième Congrèss Mondial pour la Qualité de l'Air. Proceeds. 2, 59–66.
Préndez, M.M., Ortiz, J.L., Cortés, E. and Huerta, R.: 1980, ‘Pb y Br en aerosoles atmosféricos de Santiago. Parte I’, Bol. Extr. Soc. Chil. Qca. 25, 243–245.
Préndez, M.M. and Garrido, J.I.: 1981, ‘Determinaciones de Pb en aire y sus posibles relaciones con alteraciones biológicas’, Rev. Col. Qcos. 26, 20–23.
Préndez, M.M. and Zolezzi, S.R.: 1982, ‘Composición elemental de aerosoles sub-antárticos en función del tamaño de partícula’, Bol. INACH-Serie Científica 29, 17–30.
Préndez, M.M., Ortiz, J.L., Garrido, J.I., Huerta, R., Alvarez, C. and Zolezzi, S.R.: 1983, ‘Une méthode simple pour le traitement des aérosols atmosphériques’, Radiochem. and Radioanal. Letters 56, 291–303.
Raunemaa, A., Hautojärvi, V., Hyvönen, R., Hillamo, V., Lindfors, V., Karhula, K. and Kauppinen, E.: 1983, ‘Lead and Fine Particles in the Environment of Children’, VIième Congrèss Mondial pour la Qualité de l'Air. Proceeds. 4, 169–176.
Rojas, C.M., Artaxo, P., Van Grieken, R.: 1990, ‘Aerosols in Santiago de Chile: A Study Using Receptor Modeling with X-Ray Fluorescence and Single Particle Analysis’, Atmosph. Environ. 24B, 227–241.
Stern, A.C., Boubel, R.W. and Turner, D.B.: 1984, Fundamentals of Air Pollution, 2nd. Ed., Acad. Press Inc.
Trier, A. and Silva, C.: 1987, ‘Inhalable Urban Atmospheric Particulate Matter in a Semi-Arid Climate. The Case of the Santiago de Chile’, Atmosph. Environ. 27, 977.
Ulriksen, P. and Aceituno, P.: 1975, ‘Estudios de contaminación atmosférica de Santiago desarrollados en el Departamento de Geofísica de la Universidad de Chile’, Rev. Geofísica (Mexico), No. 3.
Ulriksen, P.: 1980, ‘Variaciones diarias de la altura de la capa atmosférica superficial de mezcla sobre Santiago’, Tralka 1 (2), 143–152.
Urrutia, N.H.: 1988, ‘Contaminación por aerosoles atmosféricos: Contribución de los vehículos motorizados’, Tesis de Licenciatura en Química, Fac. Cs. Químicas y Farmacéuticas, Universidad de Chile.
Viala, A., Gouezzo, F., Charpin, D., Kleisbauer, J.P., Grimaldi, F., Fondarai, J., Francheterre A. and Mola, P.: 1983, ‘Affections respiratoires chroniques chez les chauffeurs de taxi marseillais. Role de la Pollution atmosphérique par Pb et autres facteurs environnementaux. II — Etude Toxicologique’, VIième Congrèss Mondial pour la Qualité de l'Air. Proceeds. 2, 301–304.
Volchok, H.L. and Bogen, D.C.: 1973, Atmospheric Trace Metal Studies. Chemical Analysis of the Environment and Other Modern Techniques, Plenum Press, New York.
Vostal, J.J., Taves, E., Sayre, J.N. and Charney, E.: 1974, ‘Lead Analysis of House Dust: A Method for the Detection of Another Source of Lead Exposure in Inner City Children’, Environ. Health Perspect. 24, 91–97.
Zoller, W.H., Gladney, E.S. and Duce, R.A.: 1974, ‘Atmospheric Concentration and Sources of Trace Metals at the South Pole’, Science 183, 198–200.
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Préndez, M.M., Ortiz, J.L. & Zolezzi, S.R. Evolution of lead concentration in the particulate matter of Santiago, Chile, since 1978. Environ Monit Assess 24, 99–115 (1993). https://doi.org/10.1007/BF00547982
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DOI: https://doi.org/10.1007/BF00547982