Abstract
The main characteristics of the ultraviolet absorption spectra of simple alkyl, fluorine and chlorine derivatives of silane are described. The interpretation of these spectra is discussed in relation to the respective photoelectron spectra, the Rydberg-valence-shell distinction and involvement of 3d atomic orbitals.
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Dedicated to Professor Dr. Hermann Hartmann on the occasion of his 65th birthday.
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Roberge, R., Sandorfy, C. & Strausz, O.P. The electronic spectra of the alkyl, fluorine and chlorine substituted derivatives of silane. Theoret. Chim. Acta 52, 171–179 (1979). https://doi.org/10.1007/BF00547676
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DOI: https://doi.org/10.1007/BF00547676