Abstract
Remote measurements of nitrogen dioxide (NO2) were recorded in the ‘brown cloud’ over Albuquerque, NM, using absorption spectroscopy in the winter of 1987-88 and summer of 1989. The NO2 burdens (optical densities) measured in this manner were found to be in excess of 100 ppm-m. These long pathlength measurements correspond to total concentrations of approximately 5–10 ppb over the integrated observation pathlengths, which ranged from 10–20 km. These concentrations compare well with single location, independent NO x analyses. Using two correlation (absorption) spectrometers simultaneously, it was shown that the NO2 distribution is not uniform over the city and can change on the order of minutes in the boundary layer late in the day, demonstrating the advantages of NO2 optical measurements for assessing the location and extent of urban nitrogen dioxide levels in the boundary layer.
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Countess, R.J., Wolff, G.T. and Cadle, S.H.: 1980, ‘The Denver Winter Aerosol: A Comprehensive Chemical Characterization’, J. Air. Pollut. Contr. Assoc. 30, 1194–1200.
Davies, J.H.: 1970, ‘Correlation Spectroscopy’, Anal. Chem. 42, 101A-105A, 108A, 110A, 112A.
Dzubay, T.G., Stevens, R.K. and Lewis, C.W.: 1982, ‘Visibility and Aerosol Composition in Houston, Texas’, Environ. Sci. Technol. 16, 514–525.
Ewing, G.W.: 1969, Instrumental Methods of Chemical Analysis, McGraw-Hill, New York.
Ferman, M.A., Wolff, G.T. and Kelly, N.A.: 1981, ‘An Assessment of the Gaseous Pollutants and Meteorological Conditions Associated with Denver's Brown Cloud’, J. Environ. Sci. Health A16, 315–339.
Finlayson-Pitts, B.J. and Pitts, J.N., Jr.: 1986, Atmospheric Chemistry: Fundamentals and Experimental Techniques, John Wiley and Sons, NY.
Franzblau, E. and Popp, C.J.: 1989, ‘Nitrogen Oxides Produced from Lightning’, J. Geophys. Res. 94, 11089–11104.
Galle, B., Sunesson, A. and Wendt, W.: 1988, ‘NO2-Mapping Using Laser-Radar Techniques’, Atmos. Environ. 22, 569–573.
Groblicki, P.J., Wolff, G.T. and Countess, R.J.: 1981, ‘Visibility-Reducing Species in the Denver ‘Brown Cloud’. I. Relationships Between Extinction and Chemical Composition’, Atmos. Environ. 15, 2473–2484.
Hamilton, P.M., Varey, R.H. and Millan, M.M.: 1978, ‘Remote Sensing of Sulfur Dioxide’, Atmos. Environ. 12, 127–133.
Hoff, R.M. and Millan, M.M.: 1981, ‘Remote SO2 Mass Flux Measurements Using COSPEC’, J. Air Pollut. Contr. Assoc. 31, 381–384.
Husar, R.B. and White, W.H.: 1976, ‘On the Color of the Los Angeles Smog’, Atmos. Environ. 10, 199–204.
Lewis, C.W. and Dzubay, T.G.: 1986, ‘Measurement of Light Absorption Extinction in Denver’, Aerosol Sci. Technol. 5, 325–336.
Melo, O.T. and Stevens, R.D.S.: 1981, ‘The Occurrence and Nature of Brown Plumes in Ontario’, Atmos. Environ. 15, 2521–2529.
Millan, M.M., Gallant, A.J., Chung, Y.-S. and Fanaki, F.: 1985, ‘COSPEC Observations of Mt. St. Helens Volcanic SO2 Eruption Cloud of 18 May 1980 over Southern Ontario’, Atmost. Environ. 19, 255–263.
Millan, M.M. and Hoff, R.M.: 1978, ‘Remote Sensing of Air Pollutants by Correlation Spectroscopy — Instrumental Response Characteristics’, Atmos. Environ. 12, 853–864.
Newcomb, G.S. and Millan, M.M.: 1970, ‘Theory, Applications, and Results of the Long-Line Correlation Spectrometer’, IEEE Trans. Geosci. Electr. 8, 149–157.
Rothe, K.W., Brinkman, U. and Walther, H.: 1974a, ‘Applications of Tunable Dye Lasers to Air Pollution Detection: Measurements of Atmospheric NO2 Concentrations by Differential Absorption’, Appl. Phys. 3, 115–119.
Rothe, K.W., Brinkman, U. and Walther, H.: 1974b, ‘Remote Measurement of NO2 Emission from a Chemical Factory by the Differential Absorption Technique’, Appl. Phys. 4, 181–182.
Varfalvy, L.: 1984, ‘NO to NO2 Conversion and Plume Dispersion Study at La Citiere Gas Turbine Power Station’, presented to the World Conference on Remote Sensing, October 8–11, 1984, Bayreuth, W. Germany.
Waggoner, A.P., Weiss, R.E. and Ahlquist, N.C.: 1983, ‘The Color of Denver Haze’, Atmos. Environ. 17, 2081–2086.
Williams, D.T. and Kolits, B.L.: 1968, ‘Molecular Correlation Spectrometry’, Appl. Opt. 7, 607–616.
Wolff, G.T., Countess, R.J., Groblicki, P.J., Ferman, M.A., Cadle, S.H. and Muhlbaier, J.L.: 1981, ‘Visibility-Reducing Species in the Denver ‘Brown Cloud’—II. Sources and Temporal Patterns’, Atmos. Environ. 15, 2485–2502.
Wolff, G.T., Ferman, M.A., Kelly, N.A., Stroup, D.P. and Ruthkosky, M.S.: 1982, ‘The Relationships Between the Chemical Composition of Fine Particles and Visibility in the Detroit Metropolitan Area’, J. Air. Pollut. Contr. Assoc. 32, 1216–1220.
Zak, B.D., Einfeld, W., Church, H.W., Gay, G.T., Jensen, A.L., Trijonis, J., Ivey, M.D., Homann, P.S. and Tipton, C.: 1984, ‘The Albuquerque Winter Visibility Study, Volume 1. Overview and Data Analysis’, Sandia Report SAND84-0173/1, Sandia National Laboratories, Albuquerque, NM 87185.
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Franzblau, E., Popp, C.J., Prestbo, E.W. et al. Remote measurement of NO2 in the brown cloud over Albuquerque, New Mexico. Environ Monit Assess 24, 231–242 (1993). https://doi.org/10.1007/BF00545980
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DOI: https://doi.org/10.1007/BF00545980