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Determination of iron, cobalt, copper, and zinc in the suspended phase, slime, and sludge from natural and wastewaters by the atomic absorption method

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Abstract

A comparison of the recommendations in foreign national standards and domestic experience shows that atomic absorption methods in flame (iron, zinc) and flameless atomization (cobalt, copper) are most acceptable for monitoring the concentration of iron, cobalt, copper, and zinc in natural and wastewaters, including the suspended phase, slime, and sludge. The basic stages of environmental methods of measurement (sample collection, sample preparation, and method of analysis) are discussed in consideration of foreign and domestic experience. The basic analytical parameters of the atomic absorption method metrologically investigated at the Khimvolokno Scientific and Industrial Association (SIA) and approved in the established order are reported. The suspended phase and filtrate (after separation of the suspended phase by filtration) from wastewaters from several viscose plants was analyzed. It was found that the concentration of iron, cobalt, and copper in the suspended phase was comparable to their concentration in the filtrate as soluble forms. The concentration of zinc in the suspended phase was insignificant.

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References

  1. US Standard ASTM D 1068-84, Water. Methods of Determination of Iron.

  2. French Standard NF T 90-112-86, Analysis of Waters. Determination of Heavy Metals (Cr, Mn, Fe, Co, Ni, Cu, Zn, Ag, Cd, Pb) by Atomic Absorption Spectroscopy.

  3. German Standard DIN 38406-T.22-88, Unified German Methods of Investigation of Water, Wastewater, and Slime. Determination of 33 Elements by Atomic Emission Spectroscopy with Inductively Coupled Plasma.

  4. US Standard ASTM D 4190-82, Water. Determination of Elements in Water by Emission Spectroscopy with Inductively Coupled Plasma.

  5. US Standard ASTM D 3558-82, Water and Wastewaters. Determination of Cobalt by Atomic Absorption Spectroscopy.

  6. British Standard BS 6068 sec. 2-29-87, Water Quality. Determination of Co, Ni, Cu, Zn, Cd, and Pb by Flame Atomic Absorption Spectroscopy.

  7. German Standard DIN 38406-T.16-90, Unified German Methods of Investigation of Water, Wastewaters, and Slime. Determination of Zn, Cd, Pb, Cu, Ti, Ni, and Co by Inversion Voltametry.

  8. German Standard 38406-T.78-90, Unified German Methods of Investigation of Water, Wastewaters, and Slime. Determination of Copper by Atomic Absorption Spectroscopy.

  9. German Standard DIN 38406-T.8-80, Unified German Methods of Investigation of Water, Wastewaters, and Slime. Methods of Determination of Zinc Cations.

  10. US Standard ASTM D 1691-84, Water and Wastewaters. Methods of Determination of Zinc.

  11. Hungarian Standard MSZ-08-0474/17-33, Water, Agricultural Soils. Determination of Zinc.

  12. State Sanitation Inspection (SSI), General Requirements for Standardization and Certification of Methods of Measurement, GOST 8.010-90.

  13. SSI, Metrological Certification of Methods of Measuring the Concentrations of Components of Samples of Substances and Materials, GOST 8.605-84.

  14. SSI, Requirements for Compilation, Contents, and Presentation of Documents Regulating Methods of Measuring the Concentrations of Components of Samples of Substances and Materials, GOST 8.504-84.

  15. Instruction on Taking Samples for Analysis of Wastewaters, NVN 33-5-3-01-85.

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Additional information

All-Russian Scientific-Research Institute of Polymer Fibres, Mytishchi. Translated from Khimicheskie Volokna, No. 1, pp. 56–60, January–February, 1994.

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Gorskaya, A.P., Ovechenko, I.T., Pribytkov, V.A. et al. Determination of iron, cobalt, copper, and zinc in the suspended phase, slime, and sludge from natural and wastewaters by the atomic absorption method. Fibre Chem 26, 67–71 (1994). https://doi.org/10.1007/BF00545533

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