Journal of Materials Science

, Volume 27, Issue 14, pp 3793–3798 | Cite as

Infrared and Raman spectra of binary tellurite glasses containing boron and indium oxides

  • Qiu Jian Rong
  • Akiyoshi Osaka
  • Tokuro Nanba
  • Jun Takada
  • Yoshinari Miura
Papers

Abstract

The constitution of glasses in the systems M2O3-TeO2 (M = B and In) was investigated by Raman and infrared spectroscopy. From the relation between the M2O3 content and the intensity ratios of the deconvoluted Raman peaks I(720)/I(665) and I(780)/I(665), it was concluded that In2O3 behaves as a network modifier to yield TeO3units and that discrete BO3 and BO4 units construct a network of glasses containing boron oxide. A structural model for those glasses was derived which involves three-coordinated oxygen atoms and TeO4 units of an intermediate configuration, O3Teδ+ ...Oδ-.

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References

  1. 1.
    E. F. Lambson, G. A. Saunders, B. Bridge and R. A. El-Mallawany, J. Non-Cryst. Solids 69 (1984) 117.Google Scholar
  2. 2.
    N. Mochida and K. Takahashi, Yogyo-Kyokai-Shi 86 (1978) 317.Google Scholar
  3. 3.
    T. Yoko, K. Kamiya, K. Tanaka, H. Yamada and S. Sakka, Nippon Seramikkusu Kyokai Gakujutsu Ronbunshi 97 (1989) 289.Google Scholar
  4. 4.
    M. Arnaudov, V. Dimitrov, Y. Dimitriev and L. Markova, Mater. Res. Bull. 17 (1982) 1121.Google Scholar
  5. 5.
    M. Imaoka and T. Yamasaki, Yogyo-Kyokai-Shi 76 (1968) 160.Google Scholar
  6. 6.
    H. Nasu, O. Matsusita, K. Kamiya, H. Kobayashi and K. Kubodera, J. Non-Cryst. Solids 124 (1990) 275.Google Scholar
  7. 7.
    J. E. Huheey, “Inorganic chemistry”, 3rd Edn (Harper and Row, New York, 1983) Ch. 5.Google Scholar
  8. 8.
    K. Suzuki, J. Non-Cryst. Solids 95/96 (1987) 15.Google Scholar
  9. 9.
    Y. Dimitriev, V. Dimitrov and M. Arnaudov, J. Mater. Sci. 18 (1983) 1353.Google Scholar
  10. 10.
    M. Dimitrova-Pankova, Y. Dimitrov, M. Arnaudov and V. Dimitrov, Phys. Chem. Glasses 30 (1989) 260.Google Scholar
  11. 11.
    R. Göring, H. Bürger, H. Nass and B. Schnabel, Physica Status Solidi (a) 68 (1981) k29.Google Scholar
  12. 12.
    Y. Kaneko, H. Nakamura, M. Yamane, K. Mizoguchi and Y. Suginohara, Yogyo-Kyokai-Shi 91 (1983) 321.Google Scholar
  13. 13.
    W. L. Konijnendijk and J. M. Stevels, J. Non-Cryst. Solids 18 (1975) 30.Google Scholar
  14. 14.
    A. Bhargava, R. L. Snyder and R. A. Condrate, Sr. Mater. Res. Bull. 22 (1987) 1603.Google Scholar
  15. 15.
    T. Sekiya, N. Mochida, J. Ohtsuka and M. Tonokawa, Nippon Seramikkusu Kyokai Gakujutsu Ronbunshi 97 (1989) 1435.Google Scholar
  16. 16.
    O. Lindqvist, W. Mark and J. Moret, Acta Crystallogr. B31 (1975) 1255.Google Scholar
  17. 17.
    R. Masse, J. C. Guitel and I. Tordjman, Mater. Res. Bull. 15 (1980) 431.Google Scholar
  18. 18.
    H. Meyer, Z. Kristallogr. 124 (1967) 228.Google Scholar
  19. 19.
    O. Lindqvist, Acta Chem. Scand. 22 (1968) 977.Google Scholar
  20. 20.
    B. Buss and B. Krebs, Inorg. Chem. 10 (1971) 2795.Google Scholar
  21. 21.
    B. Mysen, W. Larry, W. Finger, O. Virgo and F. A. Seifert, Amer. Mineral. 67 (1982) 686.Google Scholar
  22. 22.
    G. Menorah and J. Gary, Acta Crystallogr. B27 (1972) 602.Google Scholar
  23. 23.
    N. Mochida, T. Sekiya, J. Ohtsuka and Tonokawa, Nippon Seramikkusu Kyokai Gakujutsu Ronbunshi 96 (1988) 973.Google Scholar
  24. 24.
    J. E. Huheey, “Inorganic chemistry”, 3rd Edn (Harper and Row, New York, 1983) Ch. 3.Google Scholar

Copyright information

© Chapman & Hall 1992

Authors and Affiliations

  • Qiu Jian Rong
    • 1
  • Akiyoshi Osaka
    • 1
  • Tokuro Nanba
    • 1
  • Jun Takada
    • 1
  • Yoshinari Miura
    • 1
  1. 1.Department of Applied Chemistry, Faculty of EngineeringOkayama University 3-3-1Okayama-shiJapan

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